The image you've sent describes a quantitative analysis experiment (titration), not qualitative analysis. Assuming you're asking for the formulas relevant to the experiment shown in the image, here they are:
Formulas for the Quantitative Analysis Experiment
1. Preparation of Standard Potassium Iodate (KIO₃) Solution (Procedure 1):
- Molar Mass of KIO₃:
To calculate the molar mass, you'd sum the atomic masses of its constituent elements:
MKIO3=MK+MI+(3×MO)
Using standard atomic masses:
MKIO3=39.10g/mol+126.90g/mol+(3×16.00g/mol)=214.00 g/mol
- Moles of KIO₃:
Moles of KIO3=MolarMassofKIO3MassofKIO3(fromTable1)
- Concentration of KIO₃ solution:
The solution is made up to 250 cm³.
CKIO3=Volumeofsolution(indm3)MolesofKIO3
Volume in dm3=1000cm3/dm3250cm3=0.250dm3
2. Standardization of Sodium Thiosulphate (Na₂S₂O₃) Solution (Procedure 2):
This involves two sequential redox reactions:
- Reaction 1: Iodate reacts with Iodide in acidic medium to produce Iodine.
IO3−(aq)+5I−(aq)+6H+(aq)→3I2(aq)+3H2O(l)
- Reaction 2: Iodine is then titrated with Thiosulphate.
I2(aq)+2S2O32−(aq)→2I−(aq)+S4O62−(aq)
- Stoichiometry:
From Reaction 1, 1 mole of IO₃⁻ produces 3 moles of I₂.
From Reaction 2, 1 mole of I₂ reacts with 2 moles of S₂O₃²⁻.
Therefore, 1 mole of IO₃⁻ reacts with 3×2=6 moles of S₂O₃²⁻.
1MolesofIO3−=6MolesofS2O32−
- Calculation of Concentration of Na₂S₂O₃:
Moles of S2O32−=6×MolesofIO3−
CNa2S2O3×VNa2S2O3=6×CKIO3×VKIO3
Where VKIO3 is the volume of KIO₃ solution used (25 cm³ = 0.025 dm³) and VNa2S2O3 is the mean titre from Table 2.
CNa2S2O3=VNa2S2O36×CKIO3×VKIO3
3. Determination of Concentration of Copper (II) Sulphate (CuSO₄) Solution (Procedure 3):
This also involves two sequential redox reactions:
- Reaction 1: Copper(II) ions react with Iodide to produce Iodine.
2Cu2+(aq)+4I−(aq)→2CuI(s)+I2(aq)
- Reaction 2: Iodine is then titrated with Thiosulphate.
I2(aq)+2S2O32−(aq)→2I−(aq)+S4O62−(aq)
- Stoichiometry:
From Reaction 1, 2 moles of Cu²⁺ produce 1 mole of I₂.
From Reaction 2, 1 mole of I₂ reacts with 2 moles of S₂O₃²⁻.
Therefore, 2 moles of Cu²⁺ react with 2 moles of S₂O₃²⁻, which simplifies to a 1:1 molar ratio.