Here are the answers to the questions based on the synthetic route:
1. Name the compounds A, B, C, D, E, F and G.
- A: Ethanol
- B: Ethanoic acid
- C: Ethyl ethanoate
- D: Ethene
- E: Bromoethane
- F: Propanenitrile
- G: Propanoic acid
2. State the reagents and conditions for steps 1, 2, 3, 4, 5, 6 and 7.
- Step 1:
- Reagents: Steam (H₂O(g))
- Conditions: High temperature (e.g., 300 °C), high pressure (e.g., 60-70 atm), concentrated phosphoric(V) acid (H₃PO₄) catalyst.
- Step 2:
- Reagents: Acidified potassium dichromate(VI) (K₂Cr₂O₇/H₂SO₄) or acidified potassium manganate(VII) (KMnO₄/H₂SO₄).
- Conditions: Heat under reflux.
- Step 3:
- Reagents: Concentrated sulfuric acid (H₂SO₄)
- Conditions: Heat.
- Step 4:
- Reagents: Concentrated sulfuric acid (H₂SO₄)
- Conditions: Heat (e.g., 170 °C).
- Step 5:
- Reagents: Hydrogen bromide (HBr)
- Conditions: Room temperature.
- Step 6:
- Reagents: Potassium cyanide (KCN) or Sodium cyanide (NaCN)
- Conditions: Ethanol (solvent), heat under reflux.
- Step 7:
- Reagents: Dilute hydrochloric acid (HCl) or dilute sulfuric acid (H₂SO₄)
- Conditions: Heat under reflux.
3. Write a balanced chemical equation for the reaction in step 1.
CH₂=CH₂(g) + H₂O(g) ⇌ CH₃CH₂OH(g)
4. Write a balanced chemical equation for the reaction in step 2.
3CH₃CH₂OH(l) + 2Cr₂O₇²⁻(aq) + 16H⁺(aq) → 3CH₃COOH(l) + 4Cr³⁺(aq) + 11H₂O(l)
(Using acidified potassium dichromate(VI) as the oxidizing agent)
5. Write a balanced chemical equation for the reaction in step 3.
CH₃COOH(l) + CH₃CH₂OH(l) ⇌ CH₃COOCH₂CH₃(l) + H₂O(l)
6. Write a balanced chemical equation for the reaction in step 4.
CH₃CH₂OH(l) → CH₂=CH₂(g) + H₂O(l)
7. Write a balanced chemical equation for the reaction in step 5.
CH₂=CH₂(g) + HBr(g) → CH₃CH₂Br(l)
8. Write a balanced chemical equation for the reaction in step 6.
CH₃CH₂Br(l) + KCN(alc) → CH₃CH₂CN(l) + KBr(aq)
9. Write a balanced chemical equation for the reaction in step 7.
CH₃CH₂CN(l) + 2H₂O(l) + H⁺(aq) → CH₃CH₂COOH(l) + NH₄⁺(aq)
(This is for acidic hydrolysis)
What's next?