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Assign oxidation states to all atoms in the reactants and products.

Chemistry

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Answer

H2S\text{H}_2\text{S}

SO2\text{SO}_2

Step-by-step solution

3 steps
  1. Assign oxidation states to all atoms in the reactants and products.

    The given reaction is:

    2H2S+SO2→2H2O+3S2\text{H}_2\text{S} + \text{SO}_2 \rightarrow 2\text{H}_2\text{O} + 3\text{S}
    • In H2S\text{H}_2\text{S}: Hydrogen (H) has an oxidation state of +1. Since there are two H atoms, the total positive charge is +2. For the compound to be neutral, Sulfur (S) must have an oxidation state of -2.
    • In SO2\text{SO}_2: Oxygen (O) has an oxidation state of -2. Since there are two O atoms, the total negative charge is -4. For the compound to be neutral, Sulfur (S) must have an oxidation state of +4.
    • In H2O\text{H}_2\text{O}: Hydrogen (H) has an oxidation state of +1, and Oxygen (O) has an oxidation state of -2.
    • In S\text{S} (elemental sulfur): Elemental forms of elements have an oxidation state of 0.
  2. Identify the changes in oxidation states.

    • Sulfur in H2S\text{H}_2\text{S} changes from -2 to 0 (in elemental S). This is an increase in oxidation state.
    • Sulfur in SO2\text{SO}_2 changes from +4 to 0 (in elemental S). This is a decrease in oxidation state.
    • Hydrogen and Oxygen do not change their oxidation states.
  3. Determine the Reducing Agent (R.A.) and Oxidizing Agent (O.A.).

    • A substance that undergoes oxidation (increase in oxidation state) is the reducing agent.
    • A substance that undergoes reduction (decrease in oxidation state) is the oxidizing agent.

    Based on the changes:

    • H2S\text{H}_2\text{S} is oxidized because the oxidation state of sulfur increases from -2 to 0. Therefore, H2S\text{H}_2\text{S} is the reducing agent.

    • SO2\text{SO}_2 is reduced because the oxidation state of sulfur decreases from +4 to 0. Therefore, SO2\text{SO}_2 is the oxidizing agent.

    • Reducing Agent (R.A.): H2S\boxed{\text{H}_2\text{S}}

      • Reason: The sulfur in H2S\text{H}_2\text{S} is oxidized from an oxidation state of -2 to 0, meaning it loses electrons and causes the reduction of SO2\text{SO}_2.
    • Oxidizing Agent (O.A.): SO2\boxed{\text{SO}_2}

      • Reason: The sulfur in SO2\text{SO}_2 is reduced from an oxidation state of +4 to 0, meaning it gains electrons and causes the oxidation of H2S\text{H}_2\text{S}.
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