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h(i)

127\text{127}

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here are the chemistry answers in English:

Part a

Here are the names of processes 1-14 and their necessary reagents and conditions

  • Process 1: Addition Polymerization. Reagents: Initiator (e.g., peroxide) or Ziegler-Natta catalyst. Conditions: High pressure, high temperature.
  • Process 2: Complete Combustion. Reagents: Excess Oxygen. Conditions: Ignition/Heat.
  • Process 3: Dehydration. Reagents: Concentrated sulfuric acid (H2SO4H_2SO_4) or aluminum oxide (Al2O3Al_2O_3). Conditions: Heat (e.g., 170∘C170^\circ C for H2SO4H_2SO_4, 300−400∘C300-400^\circ C for Al2O3Al_2O_3).
  • Process 4: Esterification. Reagents: Propanoic acid (CH3CH2COOHCH_3CH_2COOH), concentrated sulfuric acid (H2SO4H_2SO_4) as catalyst. Conditions: Heat (reflux).
  • Process 5: Hydrolysis. Reagents: Water, acid (e.g., H2SO4H_2SO_4) or base (e.g., NaOHNaOH). Conditions: Heat (reflux).
  • Process 6: Hydroxylation/Oxidation. Reagents: Cold, dilute, alkaline potassium permanganate(VII) (KMnO4KMnO_4) (Baeyer's reagent). Conditions: Room temperature.
  • Process 7: Condensation Polymerization. Reagents: Terephthalic acid (benzene-1,4-dicarboxylic acid). Conditions: Heat, catalyst. (Assuming it refers to Terylene formation from Ethan-1,2-diol).
  • Process 8: Fractional Distillation. Reagents: None. Conditions: Heating.
  • Process 9: Hydrogenation. Reagents: Hydrogen gas (H2H_2). Conditions: Nickel or Platinum catalyst, heat.
  • Process 10: Fermentation. Reagents: Yeast. Conditions: Anaerobic, 37∘C37^\circ C. (Assuming Glucose to Ethanol, despite arrow direction).
  • Process 11: Condensation. Reagents: Fructose. Conditions: Enzyme. (Assuming Glucose to Sucrose).
  • Process 12: Condensation Polymerization. Reagents: Terephthalic acid (benzene-1,4-dicarboxylic acid). Conditions: Heat, catalyst.
  • Process 13: Biochemical Conversion/Reduction. Reagents: Microorganisms, reducing agents. Conditions: Specific fermentation conditions.
  • Process 14: Condensation Polymerization. Reagents: Hexamethylenediamine (hexane-1,6-diamine). Conditions: Heat, high pressure.

Part b

Here are the formulae of the specified substances

  • E: C2H4C_2H_4 (Ethene)
  • F: C2H2C_2H_2 (Ethyne)
  • G: CO2CO_2 (Carbon dioxide)
  • H: H2OH_2O (Water)
  • M: CH3CH2ONaCH_3CH_2ONa (Sodium ethoxide)
  • N: CH3COONaCH_3COONa (Sodium ethanoate)
  • P: CH4CH_4 (Methane)
  • R: H2H_2 (Hydrogen)
  • S: COCO (Carbon monoxide)
  • Q: CH3CH2COOHCH_3CH_2COOH (Propanoic acid)
  • X: CH3CH2OHCH_3CH_2OH (Ethanol)

Part c

Here are the types of reactions I-VIII and their necessary reagents and conditions

  • Reaction I: Addition Polymerization. Reagents: Initiator (e.g., peroxide) or Ziegler-Natta catalyst. Conditions: High pressure, high temperature.
  • Reaction II: Hydration. Reagents: Steam (H2O(g)H_2O(g)), concentrated phosphoric acid (H3PO4H_3PO_4) as catalyst. Conditions: High temperature (e.g., 300∘C300^\circ C), high pressure (e.g., 60−70 atm60-70 \text{ atm}).
  • Reaction III: Oxidation. Reagents: Acidified potassium dichromate(VI) (K2Cr2O7/H+K_2Cr_2O_7/H^+) or acidified potassium permanganate(VII) (KMnO4/H+KMnO_4/H^+). Conditions: Heat (reflux).
  • Reaction IV: Free Radical Substitution (Halogenation). Reagents: Bromine (Br2Br_2). Conditions: UV light (excess Br2Br_2 for hexabromoethane).
  • Reaction V: Addition (Halogenation). Reagents: Bromine (Br2Br_2). Conditions: Room temperature, in an inert solvent (e.g., CCl4CCl_4) or aqueous.
  • Reaction VI: Addition (Hydrohalogenation). Reagents: Hydrogen bromide (HBrHBr). Conditions: Room temperature.
  • Reaction VII: Decarboxylation. Reagents: Soda lime (NaOH+CaONaOH + CaO). Conditions: Heat.
  • Reaction VIII: Neutralization. Reagents: Sodium hydroxide (NaOHNaOH). Conditions: Room temperature.

Part d(i)

**Reaction IV (Ethane to C2Br6C_2Br_6) and Reaction V (Ethene to C2H4Br2C_2H_4Br_2)

Here are the differences

  • Reaction IV: This is a free radical substitution reaction involving an alkane (ethane). It requires UV light and replaces hydrogen atoms with bromine atoms.
  • Reaction V: This is an electrophilic addition reaction involving an alkene (ethene). It occurs at room temperature and adds bromine atoms across the double bond.

Part d(ii)

**Reaction VIII (Ethanoic acid + NaOH) and Process 4 (Ethanol + Propanoic acid)

  • Reaction VIII: This is a neutralization reaction between a carboxylic acid and a base, producing a salt and water.
  • Process 4: This is an esterification reaction between an alcohol and a carboxylic acid, producing an ester and water.

Part e

Here are the equations for the specified reactions and processes

  • Reaction I: nCH2=CH2→High P, T, initiator−(CH2−CH2)n−nCH_2=CH_2 \xrightarrow{\text{High P, T, initiator}} -(CH_2-CH_2)_n-
  • Reaction II: CH2=CH2(g)+H2O(g)→Conc. H3PO4,High T, PCH3CH2OH(g)CH_2=CH_2(g) + H_2O(g) \xrightarrow{\text{Conc. H}_3PO_4, \text{High T, P}} CH_3CH_2OH(g)
  • Reaction III: CH3CH2OH(aq)+2[O]→K2Cr2O7/H+,HeatCH3COOH(aq)+H2O(l)CH_3CH_2OH(aq) + 2[O] \xrightarrow{\text{K}_2Cr_2O_7/H^+, \text{Heat}} CH_3COOH(aq) + H_2O(l)
  • Reaction IV: CH3CH3(g)+6Br2(g)→UV lightC2Br6(s)+6HBr(g)CH_3CH_3(g) + 6Br_2(g) \xrightarrow{UV \text{ light}} C_2Br_6(s) + 6HBr(g)
  • Reaction V: CH2=CH2(g)+Br2(aq)→Room tempCH2Br−CH2Br(aq)CH_2=CH_2(g) + Br_2(aq) \xrightarrow{\text{Room temp}} CH_2Br-CH_2Br(aq)
  • Reaction VI: CH2=CH2(g)+HBr(g)→Room tempCH3CH2Br(g)CH_2=CH_2(g) + HBr(g) \xrightarrow{\text{Room temp}} CH_3CH_2Br(g)
  • Reaction VII: CH3COOH(s)+NaOH(s)→CaO, HeatCH4(g)+Na2CO3(s)CH_3COOH(s) + NaOH(s) \xrightarrow{\text{CaO, Heat}} CH_4(g) + Na_2CO_3(s)
  • Reaction VIII: CH3COOH(aq)+NaOH(aq)→Room tempCH3COONa(aq)+H2O(l)CH_3COOH(aq) + NaOH(aq) \xrightarrow{\text{Room temp}} CH_3COONa(aq) + H_2O(l)
  • Process 4: CH3CH2OH(l)+CH3CH2COOH(l)→Conc. H2SO4,HeatCH3CH2COOCH2CH3(l)+H2O(l)CH_3CH_2OH(l) + CH_3CH_2COOH(l) \xrightarrow{\text{Conc. H}_2SO_4, \text{Heat}} CH_3CH_2COOCH_2CH_3(l) + H_2O(l)
  • Process 5: CH3CH2COOCH2CH3(l)+H2O(l)→H+ or OH−,HeatCH3CH2COOH(l)+CH3CH2OH(l)CH_3CH_2COOCH_2CH_3(l) + H_2O(l) \xrightarrow{H^+ \text{ or } OH^-, \text{Heat}} CH_3CH_2COOH(l) + CH_3CH_2OH(l)
  • Process 6: CH2=CH2(g)+H2O(l)+[O]→Cold, dil. alk. KMnO4HOCH2−CH2OH(aq)CH_2=CH_2(g) + H_2O(l) + [O] \xrightarrow{\text{Cold, dil. alk. KMnO}_4} HOCH_2-CH_2OH(aq)
  • Process 10: C6H12O6(aq)→Yeast, 37∘C2CH3CH2OH(aq)+2CO2(g)C_6H_{12}O_6(aq) \xrightarrow{\text{Yeast, } 37^\circ C} 2CH_3CH_2OH(aq) + 2CO_2(g)

Part f(i)

**Methanol and pentan-1-ol

Here's how to differentiate the compounds

  • Physical Test: Boiling point. Methanol has a boiling point of 65∘C65^\circ C, while pentan-1-ol has a boiling point of 138∘C138^\circ C.
  • Chemical Test: Esterification with ethanoic acid. Methanol forms methyl ethanoate (fruity smell), while pentan-1-ol forms pentyl ethanoate (banana-like smell).

Part f(ii)

**Pentane and pentan-1-ol

  • Physical Test: Solubility in water. Pentane is insoluble in water, whereas pentan-1-ol is sparingly soluble due to hydrogen bonding.
  • Chemical Test: Reaction with sodium metal. Pentan-1-ol will react with sodium to produce hydrogen gas, while pentane will not react.

Part f(iii)

**Methanol and methanoic acid

  • Physical Test: Boiling point. Methanol has a boiling point of 65∘C65^\circ C, while methanoic acid has a boiling point of 101∘C101^\circ C.
  • Chemical Test: Reaction with sodium carbonate/bicarbonate. Methanoic acid will react with sodium carbonate to produce carbon dioxide gas (effervescence), while methanol will not.

Part f(iv)

**Propane and hexane

  • Physical Test: State at room temperature. Propane is a gas at room temperature, while hexane is a liquid.
  • Chemical Test: Both are alkanes and are generally unreactive with common laboratory reagents. There is no simple qualitative chemical test to differentiate them.

Part f(v)

**Ethane and ethene

  • Physical Test: Boiling point. Ethane has a boiling point of −89∘C-89^\circ C, while ethene has a boiling point of −104∘C-104^\circ C.
  • Chemical Test: Reaction with bromine water. Ethene (an alkene) will decolorize orange/brown bromine water, while ethane (an alkane) will not react in the dark.

Part f(vi)

**Ethanol and ethene

  • Physical Test: State at room temperature. Ethanol is a liquid, while ethene is a gas.
  • Chemical Test: Reaction with sodium metal. Ethanol will react with sodium to produce hydrogen gas, while ethene will not react.

Part g

Substance F (Ethyne) belongs to the Alkyne homologous series.

Part h(i)

127\text{127}

The fourth member of the homologous series to which F (Ethyne) belongs is *Pentyne

The type of reaction leading to the formation of gas P (Methane) from Ethanoic acid is *Decarboxylation

The equation is:

CH3COOH(s)+NaOH(s)→CaO, HeatCH4(g)+Na2CO3(s)CH_3COOH(s) + NaOH(s) \xrightarrow{\text{CaO, Heat}} CH_4(g) + Na_2CO_3(s)

j) The molecular formula of compound −(CH2CH2)n−-(CH_2CH_2)_n- is 3556.

  1. Calculate the molecular weight of the repeating unit CH2CH2CH_2CH_2.

    Atomic weights: C = 12, H = 1.
    Molecular weight of CH2CH2=(2×12)+(4×1)=24+4=28CH_2CH_2 = (2 \times 12) + (4 \times 1) = 24 + 4 = 28.

  2. Use the total molecular weight to find nn.

    n×28=3556n \times 28 = 3556
  3. Solve for nn.

    n=355628n = \frac{3556}{28} n=127n = 127

    The value of nn is 127\boxed{\text{127}}.

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