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3 stepshere are the chemistry answers in English:
Part a
Here are the names of processes 1-14 and their necessary reagents and conditions
- Process 1: Addition Polymerization. Reagents: Initiator (e.g., peroxide) or Ziegler-Natta catalyst. Conditions: High pressure, high temperature.
- Process 2: Complete Combustion. Reagents: Excess Oxygen. Conditions: Ignition/Heat.
- Process 3: Dehydration. Reagents: Concentrated sulfuric acid () or aluminum oxide (). Conditions: Heat (e.g., for , for ).
- Process 4: Esterification. Reagents: Propanoic acid (), concentrated sulfuric acid () as catalyst. Conditions: Heat (reflux).
- Process 5: Hydrolysis. Reagents: Water, acid (e.g., ) or base (e.g., ). Conditions: Heat (reflux).
- Process 6: Hydroxylation/Oxidation. Reagents: Cold, dilute, alkaline potassium permanganate(VII) () (Baeyer's reagent). Conditions: Room temperature.
- Process 7: Condensation Polymerization. Reagents: Terephthalic acid (benzene-1,4-dicarboxylic acid). Conditions: Heat, catalyst. (Assuming it refers to Terylene formation from Ethan-1,2-diol).
- Process 8: Fractional Distillation. Reagents: None. Conditions: Heating.
- Process 9: Hydrogenation. Reagents: Hydrogen gas (). Conditions: Nickel or Platinum catalyst, heat.
- Process 10: Fermentation. Reagents: Yeast. Conditions: Anaerobic, . (Assuming Glucose to Ethanol, despite arrow direction).
- Process 11: Condensation. Reagents: Fructose. Conditions: Enzyme. (Assuming Glucose to Sucrose).
- Process 12: Condensation Polymerization. Reagents: Terephthalic acid (benzene-1,4-dicarboxylic acid). Conditions: Heat, catalyst.
- Process 13: Biochemical Conversion/Reduction. Reagents: Microorganisms, reducing agents. Conditions: Specific fermentation conditions.
- Process 14: Condensation Polymerization. Reagents: Hexamethylenediamine (hexane-1,6-diamine). Conditions: Heat, high pressure.
Part b
Here are the formulae of the specified substances
- E: (Ethene)
- F: (Ethyne)
- G: (Carbon dioxide)
- H: (Water)
- M: (Sodium ethoxide)
- N: (Sodium ethanoate)
- P: (Methane)
- R: (Hydrogen)
- S: (Carbon monoxide)
- Q: (Propanoic acid)
- X: (Ethanol)
Part c
Here are the types of reactions I-VIII and their necessary reagents and conditions
- Reaction I: Addition Polymerization. Reagents: Initiator (e.g., peroxide) or Ziegler-Natta catalyst. Conditions: High pressure, high temperature.
- Reaction II: Hydration. Reagents: Steam (), concentrated phosphoric acid () as catalyst. Conditions: High temperature (e.g., ), high pressure (e.g., ).
- Reaction III: Oxidation. Reagents: Acidified potassium dichromate(VI) () or acidified potassium permanganate(VII) (). Conditions: Heat (reflux).
- Reaction IV: Free Radical Substitution (Halogenation). Reagents: Bromine (). Conditions: UV light (excess for hexabromoethane).
- Reaction V: Addition (Halogenation). Reagents: Bromine (). Conditions: Room temperature, in an inert solvent (e.g., ) or aqueous.
- Reaction VI: Addition (Hydrohalogenation). Reagents: Hydrogen bromide (). Conditions: Room temperature.
- Reaction VII: Decarboxylation. Reagents: Soda lime (). Conditions: Heat.
- Reaction VIII: Neutralization. Reagents: Sodium hydroxide (). Conditions: Room temperature.
Part d(i)
**Reaction IV (Ethane to ) and Reaction V (Ethene to )
Here are the differences
- Reaction IV: This is a free radical substitution reaction involving an alkane (ethane). It requires UV light and replaces hydrogen atoms with bromine atoms.
- Reaction V: This is an electrophilic addition reaction involving an alkene (ethene). It occurs at room temperature and adds bromine atoms across the double bond.
Part d(ii)
**Reaction VIII (Ethanoic acid + NaOH) and Process 4 (Ethanol + Propanoic acid)
- Reaction VIII: This is a neutralization reaction between a carboxylic acid and a base, producing a salt and water.
- Process 4: This is an esterification reaction between an alcohol and a carboxylic acid, producing an ester and water.
Part e
Here are the equations for the specified reactions and processes
- Reaction I:
- Reaction II:
- Reaction III:
- Reaction IV:
- Reaction V:
- Reaction VI:
- Reaction VII:
- Reaction VIII:
- Process 4:
- Process 5:
- Process 6:
- Process 10:
Part f(i)
**Methanol and pentan-1-ol
Here's how to differentiate the compounds
- Physical Test: Boiling point. Methanol has a boiling point of , while pentan-1-ol has a boiling point of .
- Chemical Test: Esterification with ethanoic acid. Methanol forms methyl ethanoate (fruity smell), while pentan-1-ol forms pentyl ethanoate (banana-like smell).
Part f(ii)
**Pentane and pentan-1-ol
- Physical Test: Solubility in water. Pentane is insoluble in water, whereas pentan-1-ol is sparingly soluble due to hydrogen bonding.
- Chemical Test: Reaction with sodium metal. Pentan-1-ol will react with sodium to produce hydrogen gas, while pentane will not react.
Part f(iii)
**Methanol and methanoic acid
- Physical Test: Boiling point. Methanol has a boiling point of , while methanoic acid has a boiling point of .
- Chemical Test: Reaction with sodium carbonate/bicarbonate. Methanoic acid will react with sodium carbonate to produce carbon dioxide gas (effervescence), while methanol will not.
Part f(iv)
**Propane and hexane
- Physical Test: State at room temperature. Propane is a gas at room temperature, while hexane is a liquid.
- Chemical Test: Both are alkanes and are generally unreactive with common laboratory reagents. There is no simple qualitative chemical test to differentiate them.
Part f(v)
**Ethane and ethene
- Physical Test: Boiling point. Ethane has a boiling point of , while ethene has a boiling point of .
- Chemical Test: Reaction with bromine water. Ethene (an alkene) will decolorize orange/brown bromine water, while ethane (an alkane) will not react in the dark.
Part f(vi)
**Ethanol and ethene
- Physical Test: State at room temperature. Ethanol is a liquid, while ethene is a gas.
- Chemical Test: Reaction with sodium metal. Ethanol will react with sodium to produce hydrogen gas, while ethene will not react.
Part g
Substance F (Ethyne) belongs to the Alkyne homologous series.
Part h(i)
The fourth member of the homologous series to which F (Ethyne) belongs is *Pentyne
The type of reaction leading to the formation of gas P (Methane) from Ethanoic acid is *Decarboxylation
The equation is:
j) The molecular formula of compound is 3556.
Calculate the molecular weight of the repeating unit .
Atomic weights: C = 12, H = 1.
Molecular weight of .Use the total molecular weight to find .
Solve for .
The value of is .
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