asanda, let's knock this out.
15.1
The reaction is exothermic.
The reason is that the given enthalpy change, ΔH<0, indicates that the reaction releases energy to the surroundings.
15.2
Step 1: Calculate the change in mass of the tablet.
Changeinmass=Initialmass−Finalmass
Changeinmass=2g−0.25g=1.75g
Step 2: Calculate the average rate of reaction.
Averagerate=TimetakenChangeinmass
Averagerate=30s1.75g
Averagerate=0.05833...g⋅s−1
Average rate = \text{0.058 g \cdot s^{-1}}
15.3
Step 1: Calculate the mass of calcium carbonate (CaCO3) in the tablet.
MassofCaCO3=40%of2g
MassofCaCO3=0.40×2g=0.80g
Step 2: Calculate the molar mass of CaCO3.
M(CaCO3)=M(Ca)+M(C)+3×M(O)
M(CaCO3)=40.08g/mol+12.01g/mol+3×16.00g/mol
M(CaCO3)=100.09g/mol
Step 3: Calculate the moles of CaCO3.
MolesofCaCO3=MolarmassofCaCO3MassofCaCO3
MolesofCaCO3=100.09g/mol0.80g=0.0079928...mol
Step 4: Use the mole ratio from the balanced equation to find the moles of CO2.
The balanced equation is: CaCO3(s)+2HCl(aq)→CaCl2(aq)+CO2(g)+H2O(l)
From the equation, 1 mole of CaCO3 produces 1 mole of CO2.
MolesofCO2=MolesofCaCO3=0.0079928...mol
Step 5: Calculate the volume of CO2 at STP. At STP, 1 mole of any gas occupies 22.4dm3.
VolumeofCO2=MolesofCO2×22.4dm3/mol
VolumeofCO2=0.0079928...mol×22.4dm3/mol
VolumeofCO2=0.179038...dm3
Volume of CO_2 = \text{0.179 dm^3}
Drop the next question! 📸