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A current of 2 A flows for 10 minutes. Calculate the quantity of electricity in Coulombs and Faradays, and the mass of copper deposited from a CuSO4 solution.

Chemistry

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2 parts
a

1200 C\text{1200 C}

0.0124 F\text{0.0124 F}

b

0.3968 g\text{0.3968 g}

Step-by-step solution

5 steps

Here's the solution to your problem:

Given:
Current (II) = 2 A
Time (tt) = 10 minutes
Atomic mass of Copper (CuCu) = 64 g/mol
Faraday's constant (FF) = 96,500 C/mol e−^-

Part a· 3 steps

Calculate the quantity of electricity used

  1. Convert time from minutes to seconds.

    t=10 min×60 s/mint = 10 \text{ min} \times 60 \text{ s/min} t=600 st = 600 \text{ s}
  2. Calculate the quantity of electricity in Coulombs.

    The formula for quantity of electricity is Q=I×tQ = I \times t.

    Q=2 A×600 sQ = 2 \text{ A} \times 600 \text{ s} Q=1200 CQ = \boxed{\text{1200 C}}
  3. Calculate the quantity of electricity in Faradays.

    We know that 1 Faraday (FF) = 96,500 C.

    Quantity in Faradays=Quantity in Coulombs96,500 C/F\text{Quantity in Faradays} = \frac{\text{Quantity in Coulombs}}{96,500 \text{ C/F}} Quantity in Faradays=1200 C96,500 C/F\text{Quantity in Faradays} = \frac{1200 \text{ C}}{96,500 \text{ C/F}} Quantity in Faradays≈0.0124 F\text{Quantity in Faradays} \approx \boxed{\text{0.0124 F}}

Part b

0.3968 g\text{0.3968 g}

Calculate the mass of copper deposited at the cathode

  1. Write the half-reaction for copper deposition and determine the moles of electrons required.

    The copper ions in CuSO4CuSO_4 are Cu2+Cu^{2+}.

    Cu2+(aq)+2e−→Cu(s)Cu^{2+}(aq) + 2e^- \to Cu(s)

    From the reaction, 2 moles of electrons are required to deposit 1 mole of copper.

  2. Use Faraday's laws to calculate the mass of copper deposited.

    2 moles of electrons correspond to 2×96,500 C2 \times 96,500 \text{ C} or 2 Faradays.
    1 mole of copper has a mass of 64 g.
    So, 2 Faradays deposit 64 g of copper.

    Using the quantity of electricity in Faradays from Step 3:

    Mass of Cu=(Quantity in Faradays)×Molar mass of CuMoles of electrons\text{Mass of Cu} = \left( \text{Quantity in Faradays} \right) \times \frac{\text{Molar mass of Cu}}{\text{Moles of electrons}} Mass of Cu=0.0124 F×64 g/mol2 F/mol\text{Mass of Cu} = 0.0124 \text{ F} \times \frac{64 \text{ g/mol}}{2 \text{ F/mol}} Mass of Cu=0.0124×32 g\text{Mass of Cu} = 0.0124 \times 32 \text{ g} Mass of Cu≈0.3968 g\text{Mass of Cu} \approx \boxed{\text{0.3968 g}}
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