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A gas A effuses through a porous partition in 115 s, while CO2 effuses through the same partition in 146 s. Calculate the molar mass of gas A.

Chemistry

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Answer

70.93 g/mol70.93 \text{ g/mol}

Step-by-step solution

5 steps
  1. Identify the given values and the formula.

    We are given the effusion times for gas A and CO2_2 for the same volume. Graham's Law of Effusion states that the ratio of the rates of effusion of two gases is inversely proportional to the square root of the ratio of their molar masses. Since rate is inversely proportional to time for a fixed volume, we can write:

    tCO2tA=MCO2MA\frac{t_{\text{CO}_2}}{t_A} = \sqrt{\frac{M_{\text{CO}_2}}{M_A}}

    Given:
    tA=146 st_A = 146 \text{ s}
    tCO2=115 st_{\text{CO}_2} = 115 \text{ s}

  2. Calculate the molar mass of CO2_2.

    The molar mass of carbon (C) is approximately 12.01 g/mol12.01 \text{ g/mol}.
    The molar mass of oxygen (O) is approximately 16.00 g/mol16.00 \text{ g/mol}.

    MCO2=12.01+(2×16.00)=12.01+32.00=44.01 g/molM_{\text{CO}_2} = 12.01 + (2 \times 16.00) = 12.01 + 32.00 = 44.01 \text{ g/mol}
  3. Substitute the values into Graham's Law equation.

    115 s146 s=44.01 g/molMA\frac{115 \text{ s}}{146 \text{ s}} = \sqrt{\frac{44.01 \text{ g/mol}}{M_A}}
  4. Square both sides of the equation to eliminate the square root.

    (115146)2=44.01 g/molMA\left(\frac{115}{146}\right)^2 = \frac{44.01 \text{ g/mol}}{M_A} (0.78767)2≈0.62043=44.01 g/molMA(0.78767)^2 \approx 0.62043 = \frac{44.01 \text{ g/mol}}{M_A}
  5. Solve for MAM_A.

    MA=44.01 g/mol0.62043M_A = \frac{44.01 \text{ g/mol}}{0.62043} MA≈70.93 g/molM_A \approx 70.93 \text{ g/mol}

    The molecular mass of A is approximately 70.93 g/mol.

    70.93 g/mol70.93 \text{ g/mol}
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