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A pink solid V yields a colourless liquid and a pale blue residue Y on strong heating. Addition of the liquid to Y regenerates V. Identify V and Y and explain the changes and applications.

Chemistry

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5. When a pink solid V is heated strongly it breaks down to form droplets of a colourless liquid, and a pale blue residue Y. When the liquid droplets were added back to residue Y, the pink colour of V was regained.

a) Identify:

i) Solid V: Hydrated cobalt(II) chloride (CoCl2⋅6H2O\text{CoCl}_2 \cdot 6\text{H}_2\text{O})

ii) Solid Y: Anhydrous cobalt(II) chloride (CoCl2\text{CoCl}_2)

b) What type of change does residue Y undergo when the colourless liquid was added back? Explain.
This is a chemical change.
Explanation: New chemical bonds are formed between the anhydrous cobalt(II) chloride and water molecules to form hydrated cobalt(II) chloride, which is a new chemical compound with different properties (e.g., color).

c) State one application of the change illustrated by solid V and residue Y.
Detection of water (e.g., using anhydrous cobalt(II) chloride paper as a test for water, which turns from blue to pink in its presence).

6. A sample of water at sea level was found to boil at temperatures between 102.5∘C102.5^\circ\text{C} and 104.5∘C104.5^\circ\text{C}. Explain this observation.
The water sample is impure. The presence of dissolved impurities (solutes) elevates the boiling point of water above 100∘C100^\circ\text{C} (boiling point elevation). Additionally, an impure substance boils over a range of temperatures, rather than at a single fixed temperature, which further confirms its impurity.

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