How can you prepare a named aldehyde/ and named ketone use oxidation of alcohol

Question

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Here's how you can prepare a named aldehyde and a named ketone using the oxidation of alcohols:

1. Preparation of a named aldehyde (e.g., Propanal)

Aldehydes are prepared by the mild oxidation of a primary alcohol. It's crucial to use a mild oxidizing agent to prevent further oxidation of the aldehyde to a carboxylic acid.

Choose a primary alcohol.
Let's use propan-1-ol.
$\text{CH}_3\text{CH}_2\text{CH}_2\text{OH} \quad (\text{Propan-1-ol})$
Choose a mild oxidizing agent.
Pyridinium chlorochromate (PCC) is a common reagent for this transformation.
Perform the oxidation.
When propan-1-ol is oxidized with PCC in dichloromethane ( $\text{CH}_2\text{Cl}_2$ ), it yields propanal.
$\text{CH}_3\text{CH}_2\text{CH}_2\text{OH} \xrightarrow{\text{PCC, CH}_2\text{Cl}_2} \text{CH}_3\text{CH}_2\text{CHO}$
The named aldehyde prepared is $\boxed{\mathbf{Propanal}}$ .

2. Preparation of a named ketone (e.g., Propanone)

Ketones are prepared by the oxidation of a secondary alcohol. Stronger oxidizing agents can be used here because ketones are generally resistant to further oxidation under these conditions.
Choose a secondary alcohol.
Let's use propan-2-ol.
$\text{CH}_3\text{CH(OH)}\text{CH}_3 \quad (\text{Propan-2-ol})$
Choose an oxidizing agent.
Chromic acid ( $\text{H}_2\text{CrO}_4$ , often formed in situ from $\text{Na}_2\text{Cr}_2\text{O}_7$ or $\text{K}_2\text{Cr}_2\text{O}_7$ in $\text{H}_2\text{SO}_4$ ) is a common reagent. PCC can also be used.
Perform the oxidation.
When propan-2-ol is oxidized with chromic acid, it yields propanone.
$\text{CH}_3\text{CH(OH)}\text{CH}_3 \xrightarrow{\text{H}_2\text{CrO}_4} \text{CH}_3\text{COCH}_3$
The named ketone prepared is $\boxed{\mathbf{Propanone}}$ .

How can you prepare a named aldehyde/ and named ketone use oxidation of alcohol

Answer

Step-by-step solution

Choose a primary alcohol.

Choose a mild oxidizing agent.

Perform the oxidation.

Choose a secondary alcohol.

Choose an oxidizing agent.

Perform the oxidation.

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