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Describe the components and reactions of a Zinc-copper galvanic cell, including standard electrode potentials and the overall cell potential.

Chemistry

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2 parts
iii

Zn(s)+Cu2+(aq)→Zn2+(aq)+Cu(s)\text{Zn}(s) + \text{Cu}^{2+}(aq) \to \text{Zn}^{2+}(aq) + \text{Cu}(s)

iv

1.10 V1.10 \text{ V}

Here's the solution for the Zinc-copper cell:

i)
The standard electrode potential of Zinc (−0.76 V-0.76 \text{ V}) is more negative than that of Copper (+0.34 V+0.34 \text{ V}). This means Zinc will be oxidized (anode) and Copper ions will be reduced (cathode).
W is the electrode where oxidation occurs.
The identity of W is the Zinc electrode (Zn\text{Zn}).

ii)
X is the electrolyte in the half-cell where reduction occurs. Copper ions are reduced to copper metal.
The identity of X is a Copper(II) salt solution (e.g., CuSO4(aq)\text{CuSO}_4(aq) or Cu(NO3)2(aq)\text{Cu(NO}_3)_2(aq)).

iii)
The equation for the overall cell reaction:
Anode (oxidation): Zn(s)→Zn2+(aq)+2e−\text{Zn}(s) \to \text{Zn}^{2+}(aq) + 2\text{e}^-
Cathode (reduction): Cu2+(aq)+2e−→Cu(s)\text{Cu}^{2+}(aq) + 2\text{e}^- \to \text{Cu}(s)
Overall cell reaction:

Zn(s)+Cu2+(aq)→Zn2+(aq)+Cu(s)\boxed{\text{Zn}(s) + \text{Cu}^{2+}(aq) \to \text{Zn}^{2+}(aq) + \text{Cu}(s)}

iv)
The reading on the voltmeter is the standard cell potential (Ecell∘E^\circ_{\text{cell}}).

Ecell∘=Ecathode∘−Eanode∘E^\circ_{\text{cell}} = E^\circ_{\text{cathode}} - E^\circ_{\text{anode}} Ecell∘=ECu2+/Cu∘−EZn2+/Zn∘E^\circ_{\text{cell}} = E^\circ_{\text{Cu}^{2+}/\text{Cu}} - E^\circ_{\text{Zn}^{2+}/\text{Zn}} Ecell∘=(+0.34 V)−(−0.76 V)E^\circ_{\text{cell}} = (+0.34 \text{ V}) - (-0.76 \text{ V}) Ecell∘=0.34 V+0.76 VE^\circ_{\text{cell}} = 0.34 \text{ V} + 0.76 \text{ V} Ecell∘=1.10 VE^\circ_{\text{cell}} = \boxed{1.10 \text{ V}}
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