This chemistry question involves key chemical concepts and calculations. The detailed solution below walks through each step, from identifying the reaction type to computing the final answer.

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Step 1: Understand the term "equimolar solutions". "Equimolar solutions" means that the molar concentrations of and are equal. Let this concentration be .
Step 2: Calculate the moles of ions used. Volume of ions = Moles of
Step 3: Calculate the moles of ions used. Volume of ions = Moles of
Step 4: Determine the mole ratio of to at maximum colour intensity. Maximum colour intensity indicates the stoichiometric ratio at which the complex is formed. The ratio of moles of to is: This means that one ion combines with one ion to form the complex.
Step 5: Determine the formula and charge of the complex ion. The central metal ion is . The ligand is . Since the ratio is 1:1, the complex will contain one and one . The charge of the complex is the sum of the charges of the metal ion and the ligand: Therefore, the formula of the complex ion is .
The formula of the complex ion is:
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Understand the term "equimolar solutions". "Equimolar solutions" means that the molar concentrations of Fe^3+(aq) and SCN^-(aq) are equal.
This chemistry question involves key chemical concepts and calculations. The detailed solution below walks through each step, from identifying the reaction type to computing the final answer.