Here are the solutions to the questions:
Question 1:
- A thistle funnel has a long stem and an open top, used to add liquids to a reaction vessel without a stopcock, often extending below the liquid surface to prevent gas escape.
- A dropping funnel has a stopcock to control the rate of liquid addition drop-wise, and its stem typically ends above the liquid surface.
Question 2:
a)
Step 1: Write the balanced chemical equation for the thermal decomposition of lead(II) nitrate.
\text{2Pb(NO_3)_2(s) \xrightarrow{\Delta} 2PbO(s) + 4NO_2(g) + O_2(g)}
b)
- Nitrogen(IV) oxide (NO2) can be separated from oxygen (O2) by cooling the mixture. At low temperatures, NO2 dimerizes to form colourless liquid dinitrogen tetroxide (N2O4), while oxygen remains a gas. The liquid N2O4 can then be separated.
Question 3:
a)
- The litmus solution turns red.
b)
- Sulphur(IV) oxide (SO2) is an acidic gas. When bubbled through water, it reacts to form sulphurous acid (H2SO3), which is acidic and turns litmus red.
SO2(g)+H2O(l)⇌H2SO3(aq)
Question 4:
a)
- The method of separation illustrated is Distillation.
b)
- Mixture M is likely a solution of a non-volatile solid in a liquid or a mixture of two miscible liquids with different boiling points.
c)
- An application is the purification of water (separating water from dissolved salts).
Question 5:
a) When hydrogen sulphide gas is bubbled into concentrated nitric(V) acid:
- Observation: A yellow precipitate (sulfur) is formed, and brown fumes (nitrogen dioxide) are observed.
- Explanation: Hydrogen sulphide (H2S) is oxidized to sulfur, while concentrated nitric(V) acid (HNO3) is reduced to nitrogen dioxide.
H2S(g)+2HNO3(aq)⟶S(s)+2NO2(g)+2H2O(l)
b) When hydrogen sulphide gas is bubbled into freshly prepared iron(III) chloride solution:
- Observation: The brown/yellowish-brown solution turns pale green, and a yellow precipitate (sulfur) is formed.
- Explanation: Iron(III) ions (Fe3+) are reduced to iron(II) ions (Fe2+), and hydrogen sulphide (H2S) is oxidized to sulfur.
2FeCl3(aq)+H2S(g)⟶2FeCl2(aq)+S(s)+2HCl(aq)
Question 6:
a)
- Water hardness is caused by the presence of dissolved calcium ions (Ca2+) and magnesium ions (Mg2+).
b)
- One method to remove permanent hardness is the washing soda method (adding sodium carbonate).
c)
- One advantage of drinking hard water is that it provides essential calcium and magnesium ions for healthy bones and teeth.
Question 7:
- The sample was pure water.
- Reason: The heating curve shows a sharp and constant melting point at 0∘C and a sharp and constant boiling point at 100∘C. Impure substances melt and boil over a range of temperatures.
That's 2 down. 3 left today — send the next one.