Step 1: Identify Gas K and Gas F.
- Gas K: In the roasting furnace, copper pyrites (CuFeS2) are heated in air, converting sulfides to oxides and releasing sulfur dioxide gas.
2CuFeS2(s)+4O2(g)⟶Cu2S(s)+2FeO(s)+3SO2(g)
Therefore, Gas K is sulfur dioxide.
- Gas F: Gas F is produced in Chamber W (the converter), where matte (Cu2S) is converted to blister copper. This process also releases sulfur dioxide.
2Cu2S(l)+3O2(g)⟶2Cu2O(l)+2SO2(g)
2Cu2O(l)+Cu2S(l)⟶6Cu(l)+SO2(g)
Therefore, Gas F is sulfur dioxide.
a) Identify:
- i) Gas K: SO2
- ii) Gas F: SO2
Step 2: Write equations for the reactions in the roasting furnace and absorption tower.
- i) Roasting furnace: Copper pyrites (CuFeS2) are roasted in air.
2CuFeS2(s)+4O2(g)⟶Cu2S(s)+2FeO(s)+3SO2(g)
- ii) Absorption tower: In the absorption tower, sulfur trioxide (Gas C) reacts with concentrated sulfuric acid to form oleum (Compound T).
SO3(g)+H2SO4(l)⟶H2S2O7(l)
b) Write equations for the reactions that takes place in the:
- i) Roasting furnace:
2CuFeS2(s)+4O2(g)⟶Cu2S(s)+2FeO(s)+3SO2(g)
- ii) Absorption tower:
SO3(g)+H2SO4(l)⟶H2S2O7(l)
Step 3: Write the formula of the cation present in slag M.
- Slag M is formed in the smelting furnace when iron(II) oxide (FeO) reacts with silica (SiO2) to form iron(II) silicate (FeSiO3).
FeO(s)+SiO2(s)⟶FeSiO3(l)
- In iron(II) silicate, the iron is in the +2 oxidation state.
c) Write the formula of the cation present in the slag M:
Fe2+
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