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If the rate law for a reaction is Rate = k[B]^(3/2), by what factor does the reaction rate increase if the concentration of B is doubled?

Chemistry

ScanSolve AI Answer

Answer

222\sqrt{2}

Step-by-step solution

5 steps

Here's how to determine the increase in reaction rate:

  1. Write down the initial rate law.

    The given experimental rate law is:

    Rate1=k[B]3/2\text{Rate}_1 = k[B]^{3/2}

    where [B][B] is the initial concentration of B.

  2. Write down the new rate law when the concentration of B is doubled.

    If the concentration of B is doubled, the new concentration is 2[B]2[B]. The new rate, Rate2\text{Rate}_2, will be:

    Rate2=k(2[B])3/2\text{Rate}_2 = k(2[B])^{3/2}
  3. Simplify the new rate expression.

    Rate2=k⋅23/2⋅[B]3/2\text{Rate}_2 = k \cdot 2^{3/2} \cdot [B]^{3/2}
  4. Calculate the ratio of the new rate to the initial rate to find the factor of increase.

    Rate2Rate1=k⋅23/2⋅[B]3/2k[B]3/2\frac{\text{Rate}_2}{\text{Rate}_1} = \frac{k \cdot 2^{3/2} \cdot [B]^{3/2}}{k[B]^{3/2}}

    Cancel out kk and [B]3/2[B]^{3/2}:

    Rate2Rate1=23/2\frac{\text{Rate}_2}{\text{Rate}_1} = 2^{3/2}
  5. Evaluate the numerical value.

    23/2=21⋅21/2=222^{3/2} = 2^{1} \cdot 2^{1/2} = 2\sqrt{2}

    The reaction rate will increase by a factor of 222\sqrt{2}.

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