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If the same quantity of electricity is passed through two electrolytic cells, one containing copper(II) sulfate solution and the other containing lead(II) nitrate solution, how much lead will be depos

Chemistry

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Answer

8.80 g\text{8.80 g}

Step-by-step solution

4 steps

Here's how to solve the problem using the formula mmm=ItnF\frac{m}{mm} = \frac{It}{nF}:

The problem states that the same quantity of electricity is used for both copper and lead. This means that the term ItF\frac{It}{F} is constant for both metals.
From the formula mmm=ItnF\frac{m}{mm} = \frac{It}{nF}, we can rearrange it to m⋅nmm=ItF\frac{m \cdot n}{mm} = \frac{It}{F}.
Since ItF\frac{It}{F} is constant, we can write:

mCu⋅nCummCu=mPb⋅nPbmmPb\frac{m_{Cu} \cdot n_{Cu}}{mm_{Cu}} = \frac{m_{Pb} \cdot n_{Pb}}{mm_{Pb}}
  1. Identify the known values for copper and lead.

    For Copper (Cu):

    • Mass of copper (mCum_{Cu}) = 2.70 g
    • Molar mass of copper (mmCumm_{Cu}) = 63.5 g/mol
    • Number of electrons transferred for copper (II) (nCun_{Cu}): The half-reaction is Cu2+(aq)+2e−→Cu(s)\text{Cu}^{2+}(aq) + 2e^- \to \text{Cu}(s), so nCu=2n_{Cu} = 2.

    For Lead (Pb):

    • Molar mass of lead (mmPbmm_{Pb}) = 207 g/mol
    • Number of electrons transferred for lead (II) (nPbn_{Pb}): The half-reaction is Pb2+(aq)+2e−→Pb(s)\text{Pb}^{2+}(aq) + 2e^- \to \text{Pb}(s), so nPb=2n_{Pb} = 2.
    • Mass of lead (mPbm_{Pb}) = ? (This is what we need to calculate)
  2. Substitute the known values into the equation.

    2.70 g×263.5 g/mol=mPb×2207 g/mol\frac{2.70 \text{ g} \times 2}{63.5 \text{ g/mol}} = \frac{m_{Pb} \times 2}{207 \text{ g/mol}}
  3. Solve for mPbm_{Pb}.

    Since nCu=nPb=2n_{Cu} = n_{Pb} = 2, we can cancel out the '2' from both sides of the equation:

    2.7063.5=mPb207\frac{2.70}{63.5} = \frac{m_{Pb}}{207}

    Now, isolate mPbm_{Pb}:

    mPb=2.7063.5×207m_{Pb} = \frac{2.70}{63.5} \times 207 mPb=0.042519685×207m_{Pb} = 0.042519685 \times 207 mPb=8.7965748 gm_{Pb} = 8.7965748 \text{ g}
  4. Round the answer to an appropriate number of significant figures (3 significant figures, based on 2.70 g).

    mPb≈8.80 gm_{Pb} \approx 8.80 \text{ g}

    The mass of lead that will be deposited is 8.80 g\text{8.80 g}.

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