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Calculate the number of Faradays required to discharge 6g of ion X3+ if the cost to discharge 10g of X3+ is ₦20.00.

Chemistry

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Answer

₦9.00\text{₦9.00}

Step-by-step solution

4 steps

To solve this problem, we need to use Faraday's laws of electrolysis, which relate the amount of substance discharged to the quantity of electricity passed. The cost of electricity is directly proportional to the quantity of electricity (in Faradays) required.

  1. Calculate the number of Faradays required to discharge 10g of ion X3+\text{X}^{3+}

    First, find the moles of X:

    Moles of X=Mass of XAtomic mass of X=10 g27 g/mol\text{Moles of X} = \frac{\text{Mass of X}}{\text{Atomic mass of X}} = \frac{10 \text{ g}}{27 \text{ g/mol}}

    The discharge reaction for X3+\text{X}^{3+} is:

    X3++3e−→X\text{X}^{3+} + 3\text{e}^- \to \text{X}

    This means 3 Faradays (3F) are required to discharge 1 mole of X.
    So, the Faradays required for 10g of X is:

    Faradays for X=Moles of X×Charge of X3+\text{Faradays for X} = \text{Moles of X} \times \text{Charge of X}^{3+} Faradays for X=1027 mol×3 F/mol=3027 F=109 F\text{Faradays for X} = \frac{10}{27} \text{ mol} \times 3 \text{ F/mol} = \frac{30}{27} \text{ F} = \frac{10}{9} \text{ F}
  2. Determine the cost per Faraday

    We are given that the cost to discharge 10g of X3+\text{X}^{3+} (which is 109\frac{10}{9} F) is ₦20.00.

    Cost per Faraday=Total costTotal Faradays=₦20.00109 F\text{Cost per Faraday} = \frac{\text{Total cost}}{\text{Total Faradays}} = \frac{\text{₦}20.00}{\frac{10}{9} \text{ F}} Cost per Faraday=₦20.00×910 F−1=₦2×9 F−1=₦18.00/F\text{Cost per Faraday} = \text{₦}20.00 \times \frac{9}{10} \text{ F}^{-1} = \text{₦}2 \times 9 \text{ F}^{-1} = \text{₦}18.00/\text{F}
  3. Calculate the number of Faradays required to discharge 6g of ion Y2+\text{Y}^{2+}

    First, find the moles of Y:

    Moles of Y=Mass of YAtomic mass of Y=6 g24 g/mol=14 mol=0.25 mol\text{Moles of Y} = \frac{\text{Mass of Y}}{\text{Atomic mass of Y}} = \frac{6 \text{ g}}{24 \text{ g/mol}} = \frac{1}{4} \text{ mol} = 0.25 \text{ mol}

    The discharge reaction for Y2+\text{Y}^{2+} is:

    Y2++2e−→Y\text{Y}^{2+} + 2\text{e}^- \to \text{Y}

    This means 2 Faradays (2F) are required to discharge 1 mole of Y.
    So, the Faradays required for 6g of Y is:

    Faradays for Y=Moles of Y×Charge of Y2+\text{Faradays for Y} = \text{Moles of Y} \times \text{Charge of Y}^{2+} Faradays for Y=14 mol×2 F/mol=24 F=12 F=0.5 F\text{Faradays for Y} = \frac{1}{4} \text{ mol} \times 2 \text{ F/mol} = \frac{2}{4} \text{ F} = \frac{1}{2} \text{ F} = 0.5 \text{ F}
  4. Calculate the cost to discharge 6g of ion Y2+\text{Y}^{2+}

    Using the cost per Faraday calculated in Step 2:

    Cost for Y=Faradays for Y×Cost per Faraday\text{Cost for Y} = \text{Faradays for Y} \times \text{Cost per Faraday} Cost for Y=0.5 F×₦18.00/F=₦9.00\text{Cost for Y} = 0.5 \text{ F} \times \text{₦}18.00/\text{F} = \text{₦}9.00

    The cost to discharge 6g of ion Y2+\text{Y}^{2+} is ₦9.00.

    The final answer is ₦9.00\text{₦9.00}.

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