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Calculate the pK_a of formic acid.

Chemistry

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Answer

3.01 g\text{3.01 g}

Step-by-step solution

4 steps
  1. Calculate the pKa\text{p}K_a of formic acid.

    The acid dissociation constant (KaK_a) for formic acid (HCOOH) is given as 1.77×10−41.77 \times 10^{-4}.

    pKa=−log⁡10(Ka)\text{p}K_a = -\log_{10}(K_a) pKa=−log⁡10(1.77×10−4)\text{p}K_a = -\log_{10}(1.77 \times 10^{-4}) pKa≈3.752\text{p}K_a \approx 3.752
  2. Use the Henderson-Hasselbalch equation to find the required concentration of the conjugate base ([HCOO−][\text{HCOO}^-]).

    The Henderson-Hasselbalch equation is:

    pH=pKa+log⁡10([A−][HA])\text{pH} = \text{p}K_a + \log_{10}\left(\frac{[\text{A}^-]}{[\text{HA}]}\right)

    We are given:
    pH=3\text{pH} = 3
    [HA]=[HCOOH]=0.50 M[\text{HA}] = [\text{HCOOH}] = 0.50 \text{ M}
    pKa=3.752\text{p}K_a = 3.752
    Substitute these values into the equation:

    3=3.752+log⁡10([HCOO−]0.50)3 = 3.752 + \log_{10}\left(\frac{[\text{HCOO}^-]}{0.50}\right)

    Subtract 3.752 from both sides:

    3−3.752=log⁡10([HCOO−]0.50)3 - 3.752 = \log_{10}\left(\frac{[\text{HCOO}^-]}{0.50}\right) −0.752=log⁡10([HCOO−]0.50)-0.752 = \log_{10}\left(\frac{[\text{HCOO}^-]}{0.50}\right)

    To remove the logarithm, take 10 to the power of both sides:

    10−0.752=[HCOO−]0.5010^{-0.752} = \frac{[\text{HCOO}^-]}{0.50} 0.177=[HCOO−]0.500.177 = \frac{[\text{HCOO}^-]}{0.50}

    Now, solve for [HCOO−][\text{HCOO}^-]:

    [HCOO−]=0.177×0.50 M[\text{HCOO}^-] = 0.177 \times 0.50 \text{ M} [HCOO−]=0.0885 M[\text{HCOO}^-] = 0.0885 \text{ M}
  3. Calculate the moles of sodium formate (HCOONa) needed.

    The volume of the buffer solution is 500 mL500 \text{ mL}, which is 0.500 L0.500 \text{ L}.
    Moles of HCOONa = Concentration ×\times Volume

    Moles of HCOONa=0.0885 mol/L×0.500 L\text{Moles of HCOONa} = 0.0885 \text{ mol/L} \times 0.500 \text{ L} Moles of HCOONa=0.04425 mol\text{Moles of HCOONa} = 0.04425 \text{ mol}
  4. Calculate the mass of sodium formate (HCOONa) needed.

    The molar mass of sodium formate (HCOONa) is 68.0069 g/mol68.0069 \text{ g/mol}.
    Mass = Moles ×\times Molar mass

    Mass of HCOONa=0.04425 mol×68.0069 g/mol\text{Mass of HCOONa} = 0.04425 \text{ mol} \times 68.0069 \text{ g/mol} Mass of HCOONa≈3.009 g\text{Mass of HCOONa} \approx 3.009 \text{ g}

    The mass of sodium formate needed is approximately 3.01 g3.01 \text{ g}.

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