This chemistry question involves key chemical concepts and calculations. The detailed solution below walks through each step, from identifying the reaction type to computing the final answer.

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1.1 Chemical equilibrium is a state in a reversible reaction where the rate of the forward reaction equals the rate of the reverse reaction, and the concentrations of reactants and products remain constant.
1.2 The reaction is at equilibrium during the time intervals where the concentrations of all reactants and products are constant. The concentrations are constant during the intervals:
1.3 During the interval to , the concentration of (product) decreases, and the concentrations of and (reactants) increase. This indicates that the reverse reaction is favored.
1.4 At , the temperature is decreased. The graph shows that after , the concentration of increases, and the concentrations of and decrease. This means the forward reaction is favored. Since a decrease in temperature favors the forward reaction, the forward reaction must be exothermic.
1.5 When the temperature is decreased, the system shifts to favor the reaction that releases heat (exothermic reaction) to counteract the change. Since the forward reaction is favored (indicated by the increase in product and decrease in reactants and ), the forward reaction must be exothermic.
1.6 At , the concentration of (product) decreases sharply, while the concentrations of and (reactants) increase sharply. This indicates that some of the product, , was removed from the system.
1.7 The value of for a given reaction is only affected by temperature. Since the change made at (removal of ) is not a temperature change, the value of will remain the same.
1.8 Step 1: Calculate the initial moles of and . Molar mass of Molar mass of Initial moles of Initial moles of
Step 2: Set up an ICE table using initial concentrations. Volume of container = Initial concentration of Initial concentration of Initial concentration of
The balanced equation is:
| Species | Initial (mol/dm) | Change (mol/dm) | Equilibrium (mol/dm) | | :------ | :-------------------- | :------------------- | :------------------------ | | | | | | | | | | | | | | | |
Step 3: Use the given equilibrium concentration of to find . At equilibrium, . So,
Step 4: Calculate the equilibrium concentrations of and .
Step 5: Write the expression for and substitute the equilibrium concentrations.
Rounding to three significant figures:
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1.1 Chemical equilibrium is a state in a reversible reaction where the rate of the forward reaction equals the rate of the reverse reaction, and the concentrations of reactants and products remain constant.
This chemistry question involves key chemical concepts and calculations. The detailed solution below walks through each step, from identifying the reaction type to computing the final answer.