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The general acid dissociation constant (K_a) expression for an acid HA reacting with water is:

Chemistry

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The general acid dissociation constant (KaK_a) expression for an acid HAHA reacting with water is:
HA(aq)+H2O(l)⇌H3O+(aq)+A−(aq)HA(aq) + H_2O(l) \rightleftharpoons H_3O^+(aq) + A^-(aq)
Ka=[H3O+][A−][HA]K_a = \frac{[H_3O^+][A^-]}{[HA]}

  • a) H2PO4−H_2PO_4^- (Dihydrogen phosphate ion)

    H2PO4−(aq)+H2O(l)⇌H3O+(aq)+HPO42−(aq)H_2PO_4^-(aq) + H_2O(l) \rightleftharpoons H_3O^+(aq) + HPO_4^{2-}(aq) Ka=[H3O+][HPO42−][H2PO4−]K_a = \boxed{\frac{[H_3O^+][HPO_4^{2-}]}{[H_2PO_4^-]}}
  • b) H3PO2H_3PO_2 (Hypophosphorous acid)

    H3PO2(aq)+H2O(l)⇌H3O+(aq)+H2PO2−(aq)H_3PO_2(aq) + H_2O(l) \rightleftharpoons H_3O^+(aq) + H_2PO_2^-(aq) Ka=[H3O+][H2PO2−][H3PO2]K_a = \boxed{\frac{[H_3O^+][H_2PO_2^-]}{[H_3PO_2]}}
  • c) HSO4−HSO_4^- (Hydrogen sulfate ion)

    HSO4−(aq)+H2O(l)⇌H3O+(aq)+SO42−(aq)HSO_4^-(aq) + H_2O(l) \rightleftharpoons H_3O^+(aq) + SO_4^{2-}(aq) Ka=[H3O+][SO42−][HSO4−]K_a = \boxed{\frac{[H_3O^+][SO_4^{2-}]}{[HSO_4^-]}}
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