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Using Graham's Law of Diffusion and the given atomic masses (H=1.0, C=12.0, N=14.0, O=16.0), determine which of the following gases has the lowest rate of diffusion: A. Nitrogen (N2), B. Ammonia (NH3)

Chemistry

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Answer

C

Step-by-step solution

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To determine which gas has the lowest rate of diffusion, we use Graham's Law of Diffusion, which states that the rate of diffusion of a gas is inversely proportional to the square root of its molar mass. This means that the gas with the highest molar mass will have the lowest rate of diffusion.

We need to calculate the molar mass for each gas given the atomic masses: H=1.0, C=12.0, N=14.0, O=16.0.

  1. Calculate the molar mass for each gas.

    • A. Nitrogen (N2\text{N}_2) Molar mass of N2=2×Atomic mass of N\text{N}_2 = 2 \times \text{Atomic mass of N} Molar mass of N2=2×14.0=28.0 g/mol\text{N}_2 = 2 \times 14.0 = 28.0 \text{ g/mol}

    • B. Ammonia (NH3\text{NH}_3) Molar mass of NH3=Atomic mass of N+(3×Atomic mass of H)\text{NH}_3 = \text{Atomic mass of N} + (3 \times \text{Atomic mass of H}) Molar mass of NH3=14.0+(3×1.0)=14.0+3.0=17.0 g/mol\text{NH}_3 = 14.0 + (3 \times 1.0) = 14.0 + 3.0 = 17.0 \text{ g/mol}

    • C. Oxygen (O2\text{O}_2) Molar mass of O2=2×Atomic mass of O\text{O}_2 = 2 \times \text{Atomic mass of O} Molar mass of O2=2×16.0=32.0 g/mol\text{O}_2 = 2 \times 16.0 = 32.0 \text{ g/mol}

    • D. Methane (CH4\text{CH}_4) Molar mass of CH4=Atomic mass of C+(4×Atomic mass of H)\text{CH}_4 = \text{Atomic mass of C} + (4 \times \text{Atomic mass of H}) Molar mass of CH4=12.0+(4×1.0)=12.0+4.0=16.0 g/mol\text{CH}_4 = 12.0 + (4 \times 1.0) = 12.0 + 4.0 = 16.0 \text{ g/mol}

  2. Compare the molar masses.

    • Nitrogen (N2\text{N}_2): 28.0 g/mol
    • Ammonia (NH3\text{NH}_3): 17.0 g/mol
    • Oxygen (O2\text{O}_2): 32.0 g/mol
    • Methane (CH4\text{CH}_4): 16.0 g/mol

    Oxygen (O2\text{O}_2) has the highest molar mass (32.0 g/mol) among the given options.

  3. Determine the gas with the lowest rate of diffusion.

    According to Graham's Law, the gas with the highest molar mass will have the lowest rate of diffusion. Therefore, Oxygen (O2\text{O}_2) has the lowest rate of diffusion.

    The correct option is C.

    The final answer is C\boxed{\text{C}}

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