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The Solvay process is not applicable for the manufacture of K2CO3\text{K}_2\text{CO}_3. This is because the process relies on the low solubility of sodium bicarbonate (NaHCO3\text{NaHCO}_3), which allows it to precipitate out of the solution. In contrast, potassium bicarbonate (KHCO3\text{KHCO}_3) is highly soluble in water and would not precipitate under the conditions of the Solvay process, making its separation from the solution impractical.

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