Given molar mass (M) = 74 g⁻¹ and percentage of oxygen by mass = 43.24\%.
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2.5.1
Calculate the mass of oxygen in one mole of the compound.
Given molar mass () = and percentage of oxygen by mass = .
Mass of oxygen = .Determine the number of oxygen atoms (z).
The molar mass of oxygen is .
Number of oxygen atoms () = .
So, there are 2 oxygen atoms in the compound. The formula is .Calculate the remaining mass for carbon and hydrogen.
Mass of 2 oxygen atoms = .
Remaining mass for carbon and hydrogen = .Determine the number of carbon (x) and hydrogen (y) atoms.
Let the formula for the carbon and hydrogen part be .
We know .
By trial and error, or by considering common organic structures:
If , (too many hydrogens).
If , (too many hydrogens).
If , . This gives .
This ratio () is plausible for an organic compound.Combine the atoms to form the molecular formula.
The molecular formula is .
2.5.2
The molecular formula can represent several functional isomers. Two common functional groups for this formula are carboxylic acids and esters.-
Propanoic acid (a carboxylic acid):
This is a 3-carbon chain with a carboxylic acid group.
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Methyl ethanoate (an ester):
This is an ester formed from ethanoic acid and methanol.
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