How do you get Kw=1.0×10*-14 at 25° in no 1 question

Mathematics

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Answer

Kw=1.0×10−14K_w = 1.0 \times 10^{-14}

Step-by-step solution

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The value of Kw=1.0×10−14K_w = 1.0 \times 10^{-14} at 25∘C25^\circ \text{C} comes from the autoionization of water.

  1. Water undergoes a slight autoionization, meaning it reacts with itself to form hydronium ions (H3O+\text{H}_3\text{O}^+ or simply H+\text{H}^+) and hydroxide ions (OH−\text{OH}^-).

    H2O(l)+H2O(l)⇌H3O+(aq)+OH−(aq)\text{H}_2\text{O}(l) + \text{H}_2\text{O}(l) \rightleftharpoons \text{H}_3\text{O}^+(aq) + \text{OH}^-(aq)

    This can be simplified as:

    H2O(l)⇌H+(aq)+OH−(aq)\text{H}_2\text{O}(l) \rightleftharpoons \text{H}^+(aq) + \text{OH}^-(aq)
  2. The equilibrium constant for this reaction is called the ion product of water, KwK_w.

    Kw=[H+][OH−]K_w = [\text{H}^+][\text{OH}^-]
  3. In pure water at 25∘C25^\circ \text{C}, the concentrations of H+\text{H}^+ and OH−\text{OH}^- ions are equal because they are produced in a 1:1 ratio.

    Through experimental measurements (e.g., conductivity), it's found that the concentration of each ion is 1.0×10−7 M1.0 \times 10^{-7} \text{ M}.

    [H+]=1.0×10−7 M[\text{H}^+] = 1.0 \times 10^{-7} \text{ M} [OH−]=1.0×10−7 M[\text{OH}^-] = 1.0 \times 10^{-7} \text{ M}
  4. Substitute these concentrations into the KwK_w expression.

    Kw=(1.0×10−7)(1.0×10−7)K_w = (1.0 \times 10^{-7})(1.0 \times 10^{-7}) Kw=1.0×10(−7)+(−7)K_w = 1.0 \times 10^{(-7) + (-7)} Kw=1.0×10−14K_w = 1.0 \times 10^{-14}

    Thus, at 25∘C25^\circ \text{C}, the ion product of water is Kw=1.0×10−14\boxed{K_w = 1.0 \times 10^{-14}}.

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