Here are the solutions to the questions:
1. (a) i. Starting with the first law of thermodynamic show that for polyatomic gases γ=CvCp=1.33
Step 1: State the First Law of Thermodynamics and definitions for an ideal gas.
The First Law of Thermodynamics states that the change in internal energy ΔU of a system is equal to the heat added to the system Q minus the work done by the system W:
ΔU=Q−W
For an ideal gas, the internal energy depends only on temperature, and for a small change in temperature dT, the change in internal energy is given by: