Step 1: Identify the given values and the formula for density.
The atomic mass (M) of the element is 100g/mol.
The unit cell edge length (a) is 400pm.
The crystal structure is Body-Centered Cubic (BCC), for which the number of atoms per unit cell (Z) is 2.
Avogadro's number (NA) is 6.022×1023mol−1.
The formula for the density (ρ) of a unit cell is:
ρ=a3×NAZ×M
Step 2: Convert the unit cell edge length from picometers (pm) to centimeters (cm).
1pm=10−10cm
a=400pm=400×10−10cm=4×10−8cm
Step 3: Calculate the volume of the unit cell (a3).
a3=(4×10−8cm)3=43×(10−8)3cm3=64×10−24cm3
Step 4: Substitute the values into the density formula and calculate.
ρ=(64×10−24cm3)×(6.022×1023mol−1)2×100g/mol
ρ=64×6.022×10−24+23cm3200g
ρ=64×6.022×10−1cm3200g
ρ=385.408×10−1cm3200g
ρ=38.5408cm3200g
ρ≈5.188g/cm3
Step 5: Compare the calculated density with the given options.
The calculated density is 5.188g/cm3, which matches option (c).
The final answer is c)5.188g/cm3.