a) The reaction between ethanol and ethanoic acid to produce ethyl ethanoate and water is an esterification reaction.
CH3CH2OH(l)+CH3COOH(l)⇌CH3COOCH2CH3(l)+H2O(l)
b)
Step 1: Calculate the molar mass of ethanol (CH3CH2OH).
Molar mass of C = 12.0 g/mol
Molar mass of H = 1.0 g/mol
Molar mass of O = 16.0 g/mol
M(CH3CH2OH)=(2×12.0)+(6×1.0)+(1×16.0)=24.0+6.0+16.0=46.0 g/mol
Step 2: Calculate the moles of ethanol.
Moles of ethanol=MolarmassofethanolMassofethanol=46.0g/mol23g=0.50 mol
Step 3: Determine the moles of ethyl ethanoate produced.
From the balanced chemical equation, 1 mole of ethanol reacts to produce 1 mole of ethyl ethanoate.
Moles of ethyl ethanoate=0.50 mol
Step 4: Calculate the molar mass of ethyl ethanoate (CH3COOCH2CH3 or C4H8O2).
M(CH3COOCH2CH3)=(4×12.0)+(8×1.0)+(2×16.0)=48.0+8.0+32.0=88.0 g/mol
Step 5: Calculate the theoretical yield (mass) of ethyl ethanoate.
Theoretical yield=Molesofethylethanoate×Molar mass of ethyl ethanoate
Theoretical yield=0.50mol×88.0g/mol=44.0 g
The theoretical yield of ethyl ethanoate is 44.0g.
c)
Step 1: State the actual yield and theoretical yield.
Actual yield = 33 g
Theoretical yield = 44.0 g (from part b)
Step 2: Calculate the percentage yield.
Percentage yield=TheoreticalyieldActualyield×100%
Percentage yield=44.0g33g×100%=0.75×100%=75%
The percentage yield is 75%.
d) Ethyl ethanoate belongs to the homologous series of esters.