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As a student of chemistry analyse and interpret the available data to address management concerns.

Chemistry

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Answer

93.1 g/mol\text{93.1 g/mol}

C6H7N\text{C}_6\text{H}_7\text{N}

Step-by-step solution

5 steps
  1. Determine the empirical formula of compound X.

    First, calculate the percentage of Nitrogen by subtracting the percentages of Carbon and Hydrogen from 100%.

    %N=100%−77.3%−7.58%=15.12%\% \text{N} = 100\% - 77.3\% - 7.58\% = 15.12\%

    Next, assume a 100 g sample to convert these percentages into masses, and then into moles using their respective atomic masses (C=12.01, H=1.008, N=14.01 g/mol).

    Moles of C=77.3 g12.01 g/mol=6.436 mol\text{Moles of C} = \frac{77.3 \text{ g}}{12.01 \text{ g/mol}} = 6.436 \text{ mol} Moles of H=7.58 g1.008 g/mol=7.520 mol\text{Moles of H} = \frac{7.58 \text{ g}}{1.008 \text{ g/mol}} = 7.520 \text{ mol} Moles of N=15.12 g14.01 g/mol=1.079 mol\text{Moles of N} = \frac{15.12 \text{ g}}{14.01 \text{ g/mol}} = 1.079 \text{ mol}

    Divide each mole value by the smallest number of moles (1.079 mol for Nitrogen) to find the simplest whole-number ratio of atoms.

    C:6.4361.079≈5.96≈6\text{C}: \frac{6.436}{1.079} \approx 5.96 \approx 6 H:7.5201.079≈6.97≈7\text{H}: \frac{7.520}{1.079} \approx 6.97 \approx 7 N:1.0791.079=1\text{N}: \frac{1.079}{1.079} = 1

    The empirical formula of X is C6H7N\text{C}_6\text{H}_7\text{N}.

  2. Calculate the partial pressure of compound X during steam distillation.

    In steam distillation, the total pressure (PtotalP_{\text{total}}) is the sum of the partial pressures of the immiscible components (compound X and water).

    Ptotal=PX+PwaterP_{\text{total}} = P_{\text{X}} + P_{\text{water}}

    Given Ptotal=760 mmHgP_{\text{total}} = 760 \text{ mmHg} and the saturated vapor pressure of water (PwaterP_{\text{water}}) at 98∘C98^\circ\text{C} is 734.9 mmHg734.9 \text{ mmHg}.

    PX=Ptotal−Pwater=760 mmHg−734.9 mmHg=25.1 mmHgP_{\text{X}} = P_{\text{total}} - P_{\text{water}} = 760 \text{ mmHg} - 734.9 \text{ mmHg} = 25.1 \text{ mmHg}
  3. Determine the molar mass of compound X.

    The ratio of the masses of the components in the distillate is proportional to the product of their partial pressures and molar masses.

    mXmwater=PX×MXPwater×Mwater\frac{m_{\text{X}}}{m_{\text{water}}} = \frac{P_{\text{X}} \times M_{\text{X}}}{P_{\text{water}} \times M_{\text{water}}}

    The distillate contains 85% by mass water, meaning it contains 15% by mass compound X. So, for every 15 g of X, there are 85 g of water. The molar mass of water (MwaterM_{\text{water}}) is approximately 18.015 g/mol18.015 \text{ g/mol}.

    15 g85 g=25.1 mmHg×MX734.9 mmHg×18.015 g/mol\frac{15 \text{ g}}{85 \text{ g}} = \frac{25.1 \text{ mmHg} \times M_{\text{X}}}{734.9 \text{ mmHg} \times 18.015 \text{ g/mol}}

    Rearrange the equation to solve for MXM_{\text{X}}:

    MX=1585×734.925.1×18.015 g/molM_{\text{X}} = \frac{15}{85} \times \frac{734.9}{25.1} \times 18.015 \text{ g/mol} MX=0.17647×29.27888×18.015 g/molM_{\text{X}} = 0.17647 \times 29.27888 \times 18.015 \text{ g/mol} MX≈93.07 g/molM_{\text{X}} \approx 93.07 \text{ g/mol}

    The molar mass of X is approximately 93.1 g/mol\boxed{\text{93.1 g/mol}}.

  4. Determine the molecular formula of compound X.

    Calculate the empirical formula mass (EFM) for C6H7N\text{C}_6\text{H}_7\text{N}:

    EFM=(6×12.01)+(7×1.008)+(1×14.01)=72.06+7.056+14.01=93.126 g/mol\text{EFM} = (6 \times 12.01) + (7 \times 1.008) + (1 \times 14.01) = 72.06 + 7.056 + 14.01 = 93.126 \text{ g/mol}

    Compare the calculated molar mass (MX≈93.07 g/molM_{\text{X}} \approx 93.07 \text{ g/mol}) with the empirical formula mass.

    n=Molar MassEmpirical Formula Mass=93.07 g/mol93.126 g/mol≈1n = \frac{\text{Molar Mass}}{\text{Empirical Formula Mass}} = \frac{93.07 \text{ g/mol}}{93.126 \text{ g/mol}} \approx 1

    Since nn is approximately 1, the molecular formula is the same as the empirical formula.
    The molecular formula of X is C6H7N\boxed{\text{C}_6\text{H}_7\text{N}}.

  5. Explain the associated applications of steam distillation.

    Steam distillation is a valuable purification technique for organic compounds that are immiscible with water, volatile in steam, and often sensitive to high temperatures. It allows these compounds to be distilled at a temperature lower than their normal boiling points, preventing decomposition.

    • Purification of high-boiling organic compounds: It is used to purify compounds like aniline (compound X), nitrobenzene, and other organic substances that would decompose if distilled at their normal boiling points.
    • Extraction of natural products: This method is widely employed in industries such as perfume and food to extract essential oils from plants (e.g., eucalyptus, lemon, lavender) without causing thermal degradation of the delicate compounds.
    • Separation of volatile compounds from non-volatile impurities: Steam distillation effectively separates volatile organic compounds from non-volatile impurities or inorganic salts, providing a clean product.
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