This chemistry question involves key chemical concepts and calculations. The detailed solution below walks through each step, from identifying the reaction type to computing the final answer.
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Here are the answers to the questions: b) I)* One cation whose salts are likely to have a green colour is Fe^2+. II)* Three cations whose salts are very soluble in water irrespective of the anion are Na^+, K^+, and NH_4^+. III)* An aqueous solution of an organic compound turned litmus paper from blue to red. Q3 a)* Preliminary inference: The compound is acidic. b)* Two functional groups: Carboxylic acid (-COOH) and Phenol (-OH attached to a benzene ring). c)* Reaction with 5% NaHCO_3 solution: Carboxylic acid: It will react with NaHCO_3 to produce carbon dioxide gas, observed as effervescence. Phenol: It is generally too weak an acid to react with NaHCO_3, so no observable reaction will occur. d)* Confirmatory tests: Carboxylic acid: Perform an esterification test. Heat the compound with an alcohol (e.g., ethanol) in the presence of a few drops of concentrated sulfuric acid. The formation of a sweet-smelling ester confirms the presence of a carboxylic acid. Phenol: Perform the ferric chloride test. Add a few drops of neutral ferric chloride solution to the compound. A characteristic purple, blue, or green coloration indicates the presence of a phenol. Q3 A I)* Two carbonates that do not decompose on direct heating in the solid state are Sodium carbonate (Na_2CO_3) and Potassium carbonate (K_2CO_3). II)* The class of organic compounds that normally burns with a sooty flame is Aromatic compounds (or compounds with a high carbon-to-hydrogen ratio). III)* The brown ring test is normally used to detect the presence of the nitrate ion (NO_3^-). IV)* Two cations that readily impart characteristic colour to a Bunsen flame are Sodium ion (Na^+) and Potassium ion (K^+). Q3 B I)* An unknown colourless inorganic sample in water was acidified with dilute nitric acid and 2 drops of silver nitrate (AgNO_3)_aq was added, resulting in instant formation of a precipitate. Three anions that are likely to be present in the sample are Chloride ion (Cl^-), Bromide ion (Br^-), and Iodide ion (I^-). II)* For each of the anions listed in (I), the likely colour of the precipitate formed: Cl^-: White precipitate (AgCl) Br^-: Cream precipitate (AgBr) I^-: Yellow precipitate (AgI) III)* Procedure to confirm one anion (e.g., Chloride ion): Add dilute aqueous ammonia to the white precipitate formed. If the precipitate dissolves completely, it confirms the presence of chloride ions (AgCl is soluble in dilute ammonia). That's 2 down. 3 left today — send the next one.
