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Based on the balance equation: 2x + 4y -> 3Z + 5Q and following data, calculate: a) the rate of disappearing of Y b) the rate of disappearing of X c) the rate of appearing of Z d) the rate of appearing of Q e) the overall rate of reaction

Chemistry

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4 parts
b

0.0396 M/s\text{0.0396 M/s}

c

0.0594 M/s\text{0.0594 M/s}

d

0.0991 M/s\text{0.0991 M/s}

e

0.0198 M/s\text{0.0198 M/s}

Step-by-step solution

2 steps

Here's how to calculate the rates based on the given data and balanced equation 2X+4Y→3Z+5Q2X + 4Y \rightarrow 3Z + 5Q.

The initial data for Y is:
[Y]initial=1.350 M[Y]_{initial} = 1.350 \text{ M} at tinitial=0.00 st_{initial} = 0.00 \text{ s}
[Y]final=0.407 M[Y]_{final} = 0.407 \text{ M} at tfinal=11.9 st_{final} = 11.9 \text{ s}

  1. Calculate the rate of disappearance of Y.

    The rate of disappearance of Y is given by the negative change in concentration of Y over the change in time.

    −Δ[Y]Δt=−([Y]final−[Y]initial)(tfinal−tinitial)-\frac{\Delta[Y]}{\Delta t} = -\frac{([Y]_{final} - [Y]_{initial})}{(t_{final} - t_{initial})} −Δ[Y]Δt=−(0.407 M−1.350 M)(11.9 s−0.00 s)-\frac{\Delta[Y]}{\Delta t} = -\frac{(0.407 \text{ M} - 1.350 \text{ M})}{(11.9 \text{ s} - 0.00 \text{ s})} −Δ[Y]Δt=−(−0.943 M)11.9 s-\frac{\Delta[Y]}{\Delta t} = -\frac{(-0.943 \text{ M})}{11.9 \text{ s}} −Δ[Y]Δt=0.079243697 M/s-\frac{\Delta[Y]}{\Delta t} = 0.079243697 \text{ M/s}

    Rounding to three significant figures:

    a) The rate of disappearance of Y: 0.0792 M/s\boxed{\text{0.0792 M/s}}

  2. Calculate the rates of disappearance of X and appearance of Z and Q using stoichiometry.

    The general relationship between rates for the reaction 2X+4Y→3Z+5Q2X + 4Y \rightarrow 3Z + 5Q is:

    Rate=−12Δ[X]Δt=−14Δ[Y]Δt=13Δ[Z]Δt=15Δ[Q]Δt\text{Rate} = -\frac{1}{2}\frac{\Delta[X]}{\Delta t} = -\frac{1}{4}\frac{\Delta[Y]}{\Delta t} = \frac{1}{3}\frac{\Delta[Z]}{\Delta t} = \frac{1}{5}\frac{\Delta[Q]}{\Delta t}

    b) The rate of disappearance of X:

    −Δ[X]Δt=24×(−Δ[Y]Δt)-\frac{\Delta[X]}{\Delta t} = \frac{2}{4} \times \left(-\frac{\Delta[Y]}{\Delta t}\right) −Δ[X]Δt=12×0.079243697 M/s-\frac{\Delta[X]}{\Delta t} = \frac{1}{2} \times 0.079243697 \text{ M/s} −Δ[X]Δt=0.0396218485 M/s-\frac{\Delta[X]}{\Delta t} = 0.0396218485 \text{ M/s}

    Rounding to three significant figures: 0.0396 M/s\boxed{\text{0.0396 M/s}}

    c) The rate of appearing of Z:

    Δ[Z]Δt=34×(−Δ[Y]Δt)\frac{\Delta[Z]}{\Delta t} = \frac{3}{4} \times \left(-\frac{\Delta[Y]}{\Delta t}\right) Δ[Z]Δt=34×0.079243697 M/s\frac{\Delta[Z]}{\Delta t} = \frac{3}{4} \times 0.079243697 \text{ M/s} Δ[Z]Δt=0.05943277275 M/s\frac{\Delta[Z]}{\Delta t} = 0.05943277275 \text{ M/s}

    Rounding to three significant figures: 0.0594 M/s\boxed{\text{0.0594 M/s}}

    d) The rate of appearing of Q:

    Δ[Q]Δt=54×(−Δ[Y]Δt)\frac{\Delta[Q]}{\Delta t} = \frac{5}{4} \times \left(-\frac{\Delta[Y]}{\Delta t}\right) Δ[Q]Δt=54×0.079243697 M/s\frac{\Delta[Q]}{\Delta t} = \frac{5}{4} \times 0.079243697 \text{ M/s} Δ[Q]Δt=0.09905462125 M/s\frac{\Delta[Q]}{\Delta t} = 0.09905462125 \text{ M/s}

    Rounding to three significant figures: 0.0991 M/s\boxed{\text{0.0991 M/s}}

    e) The overall rate of reaction:
    The overall rate of reaction can be calculated using any species, divided by its stoichiometric coefficient. Using Y:

    Overall Rate=−14Δ[Y]Δt\text{Overall Rate} = -\frac{1}{4}\frac{\Delta[Y]}{\Delta t} Overall Rate=14×0.079243697 M/s\text{Overall Rate} = \frac{1}{4} \times 0.079243697 \text{ M/s} Overall Rate=0.01981092425 M/s\text{Overall Rate} = 0.01981092425 \text{ M/s}

    Rounding to three significant figures: 0.0198 M/s\boxed{\text{0.0198 M/s}}

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