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Calculate the concentration of the acid solution (HY) based on the titration results and given information.

Chemistry

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Answer

0.102 mol dm−3\text{0.102 mol dm}^{-3}

6.56 g dm−3\text{6.56 g dm}^{-3}

64.3 g mol−1\text{64.3 g mol}^{-1}

Step-by-step solution

5 steps

To solve this problem, we must first make an assumption for the average volume of acid A (HY) used in the titration, as the experimental procedure in part (a) was not performed.

Assumption for part (a):
We assume that 25.00 cm³ of NaOH solution (B) was titrated with acid HY (A).
Let the average volume of acid A (HY) used from the burette be 24.50 cm3\text{24.50 cm}^3.

Given information:

  • Mass of HY dissolved to make 250 cm³ solution = 1.64 g
  • Concentration of NaOH solution (B) = 0.100 mol dm⁻³
  • Volume of NaOH solution (B) used = 25.00 cm³
  • Reaction: HY(aq)+NaOH(aq)⟶NaY(aq)+H2O(l)\text{HY}_{(\text{aq})} + \text{NaOH}_{(\text{aq})} \longrightarrow \text{NaY}_{(\text{aq})} + \text{H}_2\text{O}_{(\text{l})}
  • Relative atomic masses: H = 1.0, O = 16.0, Na = 23.0

b) From your results and the information provided, calculate the:

  1. Calculate the moles of NaOH used.

    The concentration of NaOH is given, and the volume used is the pipette volume.

    Moles of NaOH=Concentration of NaOH×Volume of NaOH\text{Moles of NaOH} = \text{Concentration of NaOH} \times \text{Volume of NaOH} nNaOH=0.100 mol dm−3×(25.001000) dm3n_{\text{NaOH}} = 0.100 \text{ mol dm}^{-3} \times \left(\frac{25.00}{1000}\right) \text{ dm}^3 nNaOH=0.100 mol dm−3×0.02500 dm3=0.002500 moln_{\text{NaOH}} = 0.100 \text{ mol dm}^{-3} \times 0.02500 \text{ dm}^3 = 0.002500 \text{ mol}
  2. Determine the moles of HY that reacted.

    From the balanced chemical equation, the mole ratio of HY to NaOH is 1:1.

    nHY=nNaOH=0.002500 moln_{\text{HY}} = n_{\text{NaOH}} = 0.002500 \text{ mol}
  3. Calculate the concentration of A (HY) in mol dm⁻³.

    This is the concentration of the acid in the burette, using the assumed average titre volume.

    Concentration of HY=Moles of HYVolume of HY used\text{Concentration of HY} = \frac{\text{Moles of HY}}{\text{Volume of HY used}} CHY=0.002500 mol(24.501000) dm3C_{\text{HY}} = \frac{0.002500 \text{ mol}}{\left(\frac{24.50}{1000}\right) \text{ dm}^3} CHY=0.002500 mol0.02450 dm3=0.10204 mol dm−3C_{\text{HY}} = \frac{0.002500 \text{ mol}}{0.02450 \text{ dm}^3} = 0.10204 \text{ mol dm}^{-3}

    Rounding to three significant figures:

    Concentration of A (HY)=0.102 mol dm−3\text{Concentration of A (HY)} = \boxed{\text{0.102 mol dm}^{-3}}
  4. Calculate the concentration of A (HY) in g dm⁻³.

    The acid HY was prepared by dissolving 1.64 g in 250 cm³ of solution.

    Concentration of HY in g dm−3=Mass of HYVolume of solution\text{Concentration of HY in g dm}^{-3} = \frac{\text{Mass of HY}}{\text{Volume of solution}} Concentration of HY in g dm−3=1.64 g(2501000) dm3\text{Concentration of HY in g dm}^{-3} = \frac{1.64 \text{ g}}{\left(\frac{250}{1000}\right) \text{ dm}^3} Concentration of HY in g dm−3=1.64 g0.250 dm3=6.56 g dm−3\text{Concentration of HY in g dm}^{-3} = \frac{1.64 \text{ g}}{0.250 \text{ dm}^3} = 6.56 \text{ g dm}^{-3} Concentration of A (HY)=6.56 g dm−3\text{Concentration of A (HY)} = \boxed{\text{6.56 g dm}^{-3}}
  5. Calculate the molar mass of the acid HY.

    The molar mass can be found by dividing the concentration in g dm⁻³ by the concentration in mol dm⁻³.

    Molar mass of HY=Concentration of HY in g dm−3Concentration of HY in mol dm−3\text{Molar mass of HY} = \frac{\text{Concentration of HY in g dm}^{-3}}{\text{Concentration of HY in mol dm}^{-3}} MHY=6.56 g dm−30.10204 mol dm−3=64.288 g mol−1M_{\text{HY}} = \frac{6.56 \text{ g dm}^{-3}}{0.10204 \text{ mol dm}^{-3}} = 64.288 \text{ g mol}^{-1}

    Rounding to three significant figures:

    Molar mass of HY=64.3 g mol−1\text{Molar mass of HY} = \boxed{\text{64.3 g mol}^{-1}}

    *c

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