Electrochemistry grade 12 notes

Chemistry

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Electrochemistry is the branch of chemistry that studies the relationship between electrical energy and chemical change.

Key concepts include:

  • Oxidation-reduction (redox) reactions: Reactions where electrons are transferred between species. Oxidation is the loss of electrons, and reduction is the gain of electrons.
  • Electrochemical cells: Devices that convert chemical energy into electrical energy (galvanic/voltaic cells) or use electrical energy to drive non-spontaneous chemical reactions (electrolytic cells).
  • Electrodes: Conductors where oxidation and reduction occur. The anode is where oxidation happens, and the cathode is where reduction happens.
  • Electrolytes: Solutions or molten salts that contain ions and can conduct electricity.
  • Standard electrode potentials: The potential difference of a half-cell under standard conditions (1 M concentration, 1 atm pressure, 25°C). These are used to calculate the overall cell potential.
  • Faraday's laws of electrolysis: Quantify the relationship between the amount of substance produced or consumed at an electrode and the quantity of electricity passed.
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