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Determine the empirical formula of iron(II) oxide and write a balanced equation for its formation.

Chemistry

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Answer

a

Fe3O4\text{Fe}_3\text{O}_4

Step-by-step solution

6 steps

Here are the answers to your questions:

Part a· 6 steps

i) Determine the empirical formula of the oxide of iron.

  1. Calculate the mass of iron (Fe).

    Mass of iron = (Mass of empty dish + residue) - Mass of empty dish
    Mass of iron = 12.66 g−10.98 g=1.68 g12.66 \text{ g} - 10.98 \text{ g} = 1.68 \text{ g}

  2. Calculate the mass of the oxide of iron.

    Mass of oxide = (Mass of empty dish + oxide of iron) - Mass of empty dish
    Mass of oxide = 13.30 g−10.98 g=2.32 g13.30 \text{ g} - 10.98 \text{ g} = 2.32 \text{ g}

  3. Calculate the mass of oxygen (O).

    Mass of oxygen = Mass of oxide - Mass of iron
    Mass of oxygen = 2.32 g−1.68 g=0.64 g2.32 \text{ g} - 1.68 \text{ g} = 0.64 \text{ g}

  4. Convert masses to moles.

    Moles of Fe = Mass of FeMolar mass of Fe=1.68 g56.0 g/mol=0.03 mol\frac{\text{Mass of Fe}}{\text{Molar mass of Fe}} = \frac{1.68 \text{ g}}{56.0 \text{ g/mol}} = 0.03 \text{ mol}
    Moles of O = Mass of OMolar mass of O=0.64 g16.0 g/mol=0.04 mol\frac{\text{Mass of O}}{\text{Molar mass of O}} = \frac{0.64 \text{ g}}{16.0 \text{ g/mol}} = 0.04 \text{ mol}

  5. Find the simplest mole ratio.

    Divide by the smallest number of moles (0.03 mol):
    Ratio of Fe = 0.030.03=1\frac{0.03}{0.03} = 1
    Ratio of O = 0.040.03≈1.333\frac{0.04}{0.03} \approx 1.333

    To get whole numbers, multiply by 3:
    Fe ratio = 1×3=31 \times 3 = 3
    O ratio = 1.333×3=41.333 \times 3 = 4

  6. Write the empirical formula.

    The empirical formula is Fe3O4\boxed{\text{Fe}_3\text{O}_4}.

Part a(ii)

Write an equation for the reaction which took place in the combustion tube.

The reaction is the formation of iron(II,III) oxide from iron and oxygen.

3Fe(s)+2O2(g)→Fe3O4(s)3\text{Fe(s)} + 2\text{O}_2\text{(g)} \rightarrow \text{Fe}_3\text{O}_4\text{(s)}

Part b(i)

Two conditions necessary for rusting to occur

Corrosive is a destructive process in which iron is converted into hydrated iron (III) oxide.

  • Oxygen (or air)
  • Water (or moisture)

Part b(ii)

Two methods used to protect iron from rusting other than painting

  • Galvanizing (coating iron with a layer of zinc)
  • Oiling/Greasing (applying a layer of oil or grease to prevent contact with air and water)

Part c

Explain why it is not advisable to wash vehicles using seawater.

Seawater contains dissolved salts, which act as electrolytes. These electrolytes increase the electrical conductivity of the water, thereby accelerating the rate of rusting (corrosion) of the metal parts of the vehicle.

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