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Calculate the equilibrium concentration of hydrogen ions, [H^+], from the given pH.

Chemistry

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Answer

0.0097 M\text{0.0097 M}

Step-by-step solution

4 steps

Here's how to calculate the initial concentration of the weak acid HA:

  1. Calculate the equilibrium concentration of hydrogen ions, [H+][H^+], from the given pH.

    The formula for pH is:

    pH=−log⁡10[H+]pH = -\log_{10}[H^+]

    Rearranging to solve for [H+][H^+]:

    [H+]=10−pH[H^+] = 10^{-pH}

    Given pH=3.4pH = 3.4:

    [H+]=10−3.4[H^+] = 10^{-3.4} [H+]≈3.98×10−4 M[H^+] \approx 3.98 \times 10^{-4} \text{ M}
  2. Write the dissociation equilibrium for the weak acid HA and set up an ICE table.

    The dissociation of a weak acid HA is:

    HA(aq)⇌H+(aq)+A−(aq)HA(aq) \rightleftharpoons H^+(aq) + A^-(aq)

    Let C0C_0 be the initial concentration of HA.

    HAH+H^+A−A^-
    Initial (I)C0C_000
    Change (C)−x-x+x+x+x+x
    Equilibrium (E)C0−xC_0 - xxxxx

    From Step 1, we know that at equilibrium, [H+]=x=3.98×10−4[H^+] = x = 3.98 \times 10^{-4} M.
    Therefore, [A−]=x=3.98×10−4[A^-] = x = 3.98 \times 10^{-4} M.

  3. Write the acid dissociation constant (KaK_a) expression and substitute the equilibrium concentrations.

    The KaK_a expression is:

    Ka=[H+][A−][HA]K_a = \frac{[H^+][A^-]}{[HA]}

    Substitute the equilibrium concentrations from the ICE table:

    Ka=(x)(x)C0−x=x2C0−xK_a = \frac{(x)(x)}{C_0 - x} = \frac{x^2}{C_0 - x}

    Given Ka=1.7×10−5K_a = 1.7 \times 10^{-5} and x=3.98×10−4x = 3.98 \times 10^{-4} M:

    1.7×10−5=(3.98×10−4)2C0−(3.98×10−4)1.7 \times 10^{-5} = \frac{(3.98 \times 10^{-4})^2}{C_0 - (3.98 \times 10^{-4})}
  4. Solve for the initial concentration, C0C_0.

    Rearrange the equation to solve for C0C_0:

    Ka(C0−x)=x2K_a (C_0 - x) = x^2 KaC0−Kax=x2K_a C_0 - K_a x = x^2 KaC0=x2+KaxK_a C_0 = x^2 + K_a x C0=x2+KaxKaC_0 = \frac{x^2 + K_a x}{K_a} C0=x2Ka+xC_0 = \frac{x^2}{K_a} + x

    Substitute the values:

    C0=(3.98×10−4)21.7×10−5+(3.98×10−4)C_0 = \frac{(3.98 \times 10^{-4})^2}{1.7 \times 10^{-5}} + (3.98 \times 10^{-4}) C0=1.58404×10−71.7×10−5+3.98×10−4C_0 = \frac{1.58404 \times 10^{-7}}{1.7 \times 10^{-5}} + 3.98 \times 10^{-4} C0=0.00931788+0.000398C_0 = 0.00931788 + 0.000398 C0=0.00971588 MC_0 = 0.00971588 \text{ M}

    Rounding to two significant figures (based on the given pH and KaK_a values):

    C0≈0.0097 MC_0 \approx 0.0097 \text{ M}

    The initial concentration of the weak acid HA is 0.0097 M\text{0.0097 M}.

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