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Ethene reacts with concentrated tetraoxosulphate (VI) acid to form ethyl hydrogen tetraoxosulphate (VI).

Chemistry

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Here's the information regarding the preparation of ethanol:

Preparation of Ethanol from Ethene via Ethyl Hydrogen Tetraoxosulphate (VI):

  1. Ethene reacts with concentrated tetraoxosulphate (VI) acid to form ethyl hydrogen tetraoxosulphate (VI).

    C2H4(g)+H2SO4(aq)⟶C2H5HSO4(aq)\text{C}_2\text{H}_{4(g)} + \text{H}_2\text{SO}_{4(aq)} \longrightarrow \text{C}_2\text{H}_5\text{HSO}_{4(aq)}
  2. The product, ethyl hydrogen tetraoxosulphate (VI), is diluted with water and boiled to yield ethanol and regenerate tetraoxosulphate (VI) acid, which can be reused.

    C2H5HSO4(aq)+H2O(l)⟶C2H5OH(aq)+H2SO4\text{C}_2\text{H}_5\text{HSO}_{4(aq)} + \text{H}_2\text{O}_{(l)} \longrightarrow \text{C}_2\text{H}_5\text{OH}_{(aq)} + \text{H}_2\text{SO}_4

    Other Methods of Preparing Ethanol in the Laboratory:

    1. By hydration: Ethene is mixed with steam in the presence of H2SO4\text{H}_2\text{SO}_4 as a catalyst at 600∘C600^\circ\text{C} and 80 atm80 \text{ atm}.

      C2H4(g)+H2O(g)→600∘C,80 atm,H2SO4C2H5OH(aq)\text{C}_2\text{H}_{4(g)} + \text{H}_2\text{O}_{(g)} \xrightarrow{600^\circ\text{C}, 80 \text{ atm}, \text{H}_2\text{SO}_4} \text{C}_2\text{H}_5\text{OH}_{(aq)}
    2. Reducing of ethanal: Ethanal is reduced using nascent hydrogen in the presence of a nickel catalyst.

      CH3CHO(g)+H2(g)⟶C2H5OH(aq)\text{CH}_3\text{CHO}_{(g)} + \text{H}_{2(g)} \longrightarrow \text{C}_2\text{H}_5\text{OH}_{(aq)}
    3. By hydrolysis of iodoethane: Iodoethane undergoes hydrolysis using alkalis.

      C2H5I(l)+NaOH(aq)⟶C2H5OH(aq)+NaI(s)\text{C}_2\text{H}_5\text{I}_{(l)} + \text{NaOH}_{(aq)} \longrightarrow \text{C}_2\text{H}_5\text{OH}_{(aq)} + \text{NaI}_{(s)}
    4. By hydrolysis of esters: Esters are hydrolyzed using hot alkalis.

      CH3COOC2H5(aq)+NaOH(aq)⟶C2H5OH(aq)+CH3COONa(s)\text{CH}_3\text{COOC}_2\text{H}_{5(aq)} + \text{NaOH}_{(aq)} \longrightarrow \text{C}_2\text{H}_5\text{OH}_{(aq)} + \text{CH}_3\text{COONa}_{(s)}

    Industrial Preparation of Ethanol:

    Ethanol is produced commercially by a process involving the breaking down or slow decomposition of complex organic matter.

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