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Which pair of species has the same percentage composition of carbon, hydrogen, and oxygen?

Chemistry

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2 parts
1

Option (1)\text{Option (1)}

2

Option (2)\text{Option (2)}

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Part 1· 2 steps

The pair of species having same percentage composition of carbon, hydrogen, and oxygen.

To have the same percentage composition, the compounds must have the same empirical formula.

  1. Determine the molecular formula and then the empirical formula for each compound in the options.

    • Option (1): CH3COOH\text{CH}_3\text{COOH} and C6H12O6\text{C}_6\text{H}_{12}\text{O}_6

      • For CH3COOH\text{CH}_3\text{COOH}: Molecular formula is C2H4O2\text{C}_2\text{H}_4\text{O}_2.
        • Empirical formula: Divide subscripts by 2, which gives CH2O\text{CH}_2\text{O}.
      • For C6H12O6\text{C}_6\text{H}_{12}\text{O}_6: Molecular formula is C6H12O6\text{C}_6\text{H}_{12}\text{O}_6.
        • Empirical formula: Divide subscripts by 6, which gives CH2O\text{CH}_2\text{O}.
      • Both compounds have the same empirical formula (CH2O\text{CH}_2\text{O}).
    • Option (2): CH3COOH\text{CH}_3\text{COOH} and C2H5OH\text{C}_2\text{H}_5\text{OH}

      • For CH3COOH\text{CH}_3\text{COOH}: Empirical formula is CH2O\text{CH}_2\text{O}.
      • For C2H5OH\text{C}_2\text{H}_5\text{OH}: Molecular formula is C2H6O\text{C}_2\text{H}_6\text{O}.
        • Empirical formula: Cannot be simplified, so C2H6O\text{C}_2\text{H}_6\text{O}.
      • The empirical formulas are different.
    • Option (3): HCOOCH3\text{HCOOCH}_3 and C12H22O11\text{C}_{12}\text{H}_{22}\text{O}_{11}

      • For HCOOCH3\text{HCOOCH}_3: Molecular formula is C2H4O2\text{C}_2\text{H}_4\text{O}_2.
        • Empirical formula: CH2O\text{CH}_2\text{O}.
      • For C12H22O11\text{C}_{12}\text{H}_{22}\text{O}_{11}: Molecular formula is C12H22O11\text{C}_{12}\text{H}_{22}\text{O}_{11}.
        • Empirical formula: Cannot be simplified, so C12H22O11\text{C}_{12}\text{H}_{22}\text{O}_{11}.
      • The empirical formulas are different.
    • Option (4): C6H12O6\text{C}_6\text{H}_{12}\text{O}_6 and C12H22O11\text{C}_{12}\text{H}_{22}\text{O}_{11}

      • For C6H12O6\text{C}_6\text{H}_{12}\text{O}_6: Empirical formula is CH2O\text{CH}_2\text{O}.
      • For C12H22O11\text{C}_{12}\text{H}_{22}\text{O}_{11}: Empirical formula is C12H22O11\text{C}_{12}\text{H}_{22}\text{O}_{11}.
      • The empirical formulas are different.
  2. Identify the option where both compounds have the same empirical formula.

    Option (1) is the only pair where both compounds have the same empirical formula (CH2O\text{CH}_2\text{O}). Therefore, they will have the same percentage composition of carbon, hydrogen, and oxygen.

    The final answer is Option (1)\boxed{\text{Option (1)}}.


Part 2

Option (2)\text{Option (2)}

A compound prepared as a model of had 4.6% iron by mass if the compound is known to contain a single iron atom, which of these values would be closest to its molar mass?

  1. Identify the given information.

    • Percentage of iron (Fe\text{Fe}) by mass = 4.6%4.6\%
    • Number of iron atoms per molecule = 1
    • Atomic mass of iron (Fe\text{Fe}) ≈55.845 g/mol\approx 55.845 \text{ g/mol} (we can use 56 g/mol56 \text{ g/mol} for approximation as it's a multiple choice question).
  2. Use the formula for percentage by mass.

    The percentage by mass of an element in a compound is given by:

    Percentage by mass of element=mass of element in one mole of compoundmolar mass of compound×100%\text{Percentage by mass of element} = \frac{\text{mass of element in one mole of compound}}{\text{molar mass of compound}} \times 100\%

    Since there is one iron atom per molecule, the mass of iron in one mole of the compound is the atomic mass of iron. Let MM be the molar mass of the compound.

    4.6%=Atomic mass of FeM×100%4.6\% = \frac{\text{Atomic mass of Fe}}{M} \times 100\%
  3. Substitute the values and solve for MM.

    Using the atomic mass of Fe=56 g/mol\text{Fe} = 56 \text{ g/mol}:

    4.6=56 g/molM×1004.6 = \frac{56 \text{ g/mol}}{M} \times 100 M=56 g/mol4.6×100M = \frac{56 \text{ g/mol}}{4.6} \times 100 M=56004.6 g/molM = \frac{5600}{4.6} \text{ g/mol} M≈1217.39 g/molM \approx 1217.39 \text{ g/mol}
  4. Compare the calculated molar mass with the given options.

    The calculated molar mass is approximately 1217.39 g/mol1217.39 \text{ g/mol}.
    The options are:
    (1) 1000 g mol−11000 \text{ g mol}^{-1}
    (2) 1217 g mol−11217 \text{ g mol}^{-1}
    (3) 1400 g mol−11400 \text{ g mol}^{-1}
    (4) 1600 g mol−11600 \text{ g mol}^{-1}

    The closest value to 1217.39 g/mol1217.39 \text{ g/mol} is 1217 g mol−11217 \text{ g mol}^{-1}.

    The final answer is Option (2)\boxed{\text{Option (2)}}.

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