Q11. An 8.4g sample of hydrogen (H, containing carbon and hydrogen atoms only) contains 7.2g of carbon (C).
(Relative atomic mass of hydrogen (H) = 1 and carbon (C) = 12)
a. What is the empirical formula of this compound?
Step 1: Calculate the mass of hydrogen (H).
The total mass of the compound is 8.4 g, and the mass of carbon is 7.2 g.
MassofH=Totalmassofcompound−MassofCMassofH=8.4g−7.2gMassofH=1.2g
Step 2: Convert the mass of each element to moles.
MolesofC=RelativeatomicmassofCMassofC=12g/mol7.2g=0.6molMolesofH=RelativeatomicmassofHMassofH=1g/mol1.2g=1.2mol
Step 3: Find the simplest whole number ratio of moles.
Divide the number of moles of each element by the smallest number of moles (which is 0.6 mol).
RatioofC=0.6mol0.6mol=1RatioofH=0.6mol1.2mol=2
The simplest whole number ratio of C:H is 1:2.
Step 4: Write the empirical formula.
The empirical formula is CH2.
b. If this compound has a molar mass of 84, what is its molecular formula?
Step 1: Calculate the empirical formula mass.
Empirical formula = CH2
Empiricalformulamass=(1×RelativeatomicmassofC)+(2×RelativeatomicmassofH)Empiricalformulamass=(1×12)+(2×1)Empiricalformulamass=12+2=14g/mol
Step 2: Determine the ratio (n) between the molar mass and the empirical formula mass.
Given molar mass = 84 g/mol.
n=EmpiricalformulamassMolarmassn=14g/mol84g/moln=6
Step 3: Multiply the subscripts in the empirical formula by n to get the molecular formula.
Molecular formula = (Empiricalformula)n=(CH2)6
Molecular formula = \text{C_6H_{12}}