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The problem states that P, Q, R, X are four elements with atomic numbers 5, 9, 11, and 12. The compound is given as PQ₃. This formula suggests that P has a valency of 3 and Q has a valency of 1.

Chemistry

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Answer

গ) 9\text{গ) 9}

Step-by-step solution

4 steps
  1. Identify the elements P and Q.

    The problem states that P, Q, R, X are four elements with atomic numbers 5, 9, 11, and 12. The compound is given as PQ₃. This formula suggests that P has a valency of 3 and Q has a valency of 1.

    • Element with atomic number 5 is Boron (B), which has 3 valence electrons and typically forms 3 bonds.
    • Element with atomic number 9 is Fluorine (F), which has 7 valence electrons and typically forms 1 bond.
    • Element with atomic number 11 is Sodium (Na), which has 1 valence electron.
    • Element with atomic number 12 is Magnesium (Mg), which has 2 valence electrons. Based on the formula PQ₃, P is likely Boron (atomic number 5) and Q is Fluorine (atomic number 9). The compound is therefore BF₃.
  2. Determine the number of lone pairs on the central atom (P).

    In BF₃, Boron (P) is the central atom.
    Boron has 3 valence electrons.
    It forms 3 single bonds with 3 Fluorine atoms.
    All 3 valence electrons of Boron are used in bonding.
    Number of lone pairs on Boron = Valence electrons−Electrons used in bonding2=3−32=0\frac{\text{Valence electrons} - \text{Electrons used in bonding}}{2} = \frac{3 - 3}{2} = 0.

  3. Determine the number of lone pairs on the surrounding atoms (Q).

    There are 3 Fluorine (Q) atoms. Each Fluorine atom has 7 valence electrons.
    Each Fluorine atom forms 1 single bond with Boron.
    Number of electrons used by each Fluorine in bonding = 1.
    Number of lone pairs on each Fluorine atom = Valence electrons−Electrons used in bonding2=7−12=62=3\frac{\text{Valence electrons} - \text{Electrons used in bonding}}{2} = \frac{7 - 1}{2} = \frac{6}{2} = 3.

  4. Calculate the total number of lone pairs in the PQ₃ molecule.

    Total lone pairs = (Lone pairs on P) + (Number of Q atoms ×\times Lone pairs on each Q atom)
    Total lone pairs = 0+(3×3)=0+9=90 + (3 \times 3) = 0 + 9 = 9.

    The total number of lone pairs in the PQ₃ molecule is 9.

    The final answer is গ) 9\text{গ) 9}.

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