To determine the enthalpy change for the reaction using bond energies, we use the formula:
ΔHreaction∘=∑(Bondenergiesofbondsbroken)−∑(Bondenergiesofbondsformed)
The reaction is:
CH₃COCH₃ + NH₂OH → (CH₃)₂C=NOH + H₂O
First, let's identify all the bonds in the reactants and products.
Reactants:
- CH₃COCH₃ (Propanone)
- 6 C-H bonds
- 2 C-C bonds
- 1 C=O bond
- NH₂OH (Hydroxylamine)
- 2 N-H bonds
- 1 N-O bond
- 1 O-H bond
Total bonds in reactants:
- 6 C-H
- 2 C-C
- 1 C=O
- 2 N-H
- 1 N-O
- 1 O-H
Products:
- (CH₃)₂C=NOH (Propanone oxime)
- 6 C-H bonds
- 2 C-C bonds
- 1 C=N bond
- 1 N-O bond
- 1 O-H bond
- H₂O (Water)
Total bonds in products: