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Using Graham's Law of Effusion, calculate the molar mass of gas A, given that it takes 146 s to effuse, while CO2 takes 115 s to effuse under the same conditions.

Chemistry

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Answer

70.9 g/mol\text{70.9 g/mol}

Step-by-step solution

3 steps

Here's how to calculate the molecular mass of gas A:

  1. State Graham's Law of Effusion.

    Graham's Law states that the rate of effusion of a gas is inversely proportional to the square root of its molar mass. For two gases, A and B, effusing under identical conditions:

    RateARateB=MBMA\frac{\text{Rate}_A}{\text{Rate}_B} = \sqrt{\frac{M_B}{M_A}}

    Since the volume effused is the same for both gases, the rate is inversely proportional to the time taken for effusion (Rate=VolumeTime\text{Rate} = \frac{\text{Volume}}{\text{Time}}). Therefore, we can write:

    tBtA=MBMA\frac{t_B}{t_A} = \sqrt{\frac{M_B}{M_A}}

    Where tAt_A and tBt_B are the times for effusion, and MAM_A and MBM_B are the molar masses.

  2. Calculate the molar mass of CO2_2.

    The atomic mass of Carbon (C) is approximately 12.01 g/mol12.01 \text{ g/mol}.
    The atomic mass of Oxygen (O) is approximately 16.00 g/mol16.00 \text{ g/mol}.

    MCO2=12.01+(2×16.00)=12.01+32.00=44.01 g/molM_{\text{CO}_2} = 12.01 + (2 \times 16.00) = 12.01 + 32.00 = 44.01 \text{ g/mol}
  3. Substitute the known values into Graham's Law and solve for MAM_A.

    Given:
    tA=146 st_A = 146 \text{ s}
    tCO2=115 st_{\text{CO}_2} = 115 \text{ s}
    MCO2=44.01 g/molM_{\text{CO}_2} = 44.01 \text{ g/mol}

    115 s146 s=44.01 g/molMA\frac{115 \text{ s}}{146 \text{ s}} = \sqrt{\frac{44.01 \text{ g/mol}}{M_A}}

    Square both sides of the equation:

    (115146)2=44.01 g/molMA\left(\frac{115}{146}\right)^2 = \frac{44.01 \text{ g/mol}}{M_A} (0.78767)2=44.01 g/molMA(0.78767)^2 = \frac{44.01 \text{ g/mol}}{M_A} 0.62043=44.01 g/molMA0.62043 = \frac{44.01 \text{ g/mol}}{M_A}

    Now, solve for MAM_A:

    MA=44.01 g/mol0.62043M_A = \frac{44.01 \text{ g/mol}}{0.62043} MA≈70.93 g/molM_A \approx 70.93 \text{ g/mol}

    The molecular mass of gas A is 70.9 g/mol\text{70.9 g/mol}.

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