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28. (d)

  • (i) Substance T is Ethanol.
  • (ii) The property of ethene that allows it to be collected as shown in the setup is that it is insoluble or sparingly soluble in water.

28. (e)

  • The name of the polymer formed is Poly(ethene) or Polyethylene.
  • One disadvantage of this polymer is that it is non-biodegradable, leading to environmental pollution.

29.

  1. Determine the molecular formula of the hydrocarbon.

    Given the molecular mass is 58. The atomic mass of C is 12 and H is 1.
    For a hydrocarbon CxHy\text{C}_x\text{H}_y, the molecular mass is 12x+y12x + y.

    12x+y=5812x + y = 58

    By trial and error, if we assume x=4x=4:

    12(4)+y=5812(4) + y = 58 48+y=5848 + y = 58 y=58−48y = 58 - 48 y=10y = 10

    So, the molecular formula is C4H10\text{C}_4\text{H}_{10}.

  2. Draw two possible structures and name them.

    The molecular formula C4H10\text{C}_4\text{H}_{10} corresponds to an alkane.

    1. Butane (or n-butane) CH3−CH2−CH2−CH3\text{CH}_3-\text{CH}_2-\text{CH}_2-\text{CH}_3
    2. 2-Methylpropane (or isobutane) CH3−CH(CH3)−CH3\text{CH}_3-\text{CH}(\text{CH}_3)-\text{CH}_3

    30. (a)

  3. Write the reaction of ethyne with hydrogen bromide.

    Ethyne (CH≡CH\text{CH}\equiv\text{CH}) undergoes an addition reaction with hydrogen bromide (HBr\text{HBr}).

    CH≡CH+HBr→CH2=CHBr\text{CH}\equiv\text{CH} + \text{HBr} \rightarrow \text{CH}_2=\text{CHBr}
  4. State the structure and name of the product.

    The structure of the compound formed is:

    CH2=CHBr\text{CH}_2=\text{CHBr}

    The name of the compound is Bromoethene (or Vinyl bromide).

    30. (b)

  5. Identify the molecular formula.

    The molecular formula of the alkyne is C4H6\text{C}_4\text{H}_6.

  6. Draw two possible structures for alkynes with this formula.

    1. But-1-yne CH≡C−CH2−CH3\text{CH}\equiv\text{C}-\text{CH}_2-\text{CH}_3
    2. But-2-yne CH3−C≡C−CH3\text{CH}_3-\text{C}\equiv\text{C}-\text{CH}_3
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