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Solve the redox equation in English

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To balance the redox equation Zn+BrO3−→Zn2++Br−\text{Zn} + \text{BrO}_3^- \rightarrow \text{Zn}^{2+} + \text{Br}^-, we will use the half-reaction method in an acidic medium.

  1. Separate the equation into half-reactions for oxidation and reduction.

    Oxidation: Zn→Zn2+\text{Zn} \rightarrow \text{Zn}^{2+}
    Reduction: BrO3−→Br−\text{BrO}_3^- \rightarrow \text{Br}^-

  2. Balance atoms other than oxygen and hydrogen.

    The zinc (Zn) and bromine (Br) atoms are already balanced in each half-reaction.

  3. Balance oxygen (O) atoms by adding water molecules (H2O\text{H}_2\text{O}).

    Oxidation: Zn→Zn2+\text{Zn} \rightarrow \text{Zn}^{2+} (no oxygen atoms)
    Reduction: BrO3−→Br−+3H2O\text{BrO}_3^- \rightarrow \text{Br}^- + 3\text{H}_2\text{O} (3 oxygen atoms on the left, so add 3 H2O\text{H}_2\text{O} on the right)

  4. Balance hydrogen (H) atoms by adding hydrogen ions (H+\text{H}^+).

    Oxidation: Zn→Zn2+\text{Zn} \rightarrow \text{Zn}^{2+} (no hydrogen atoms)
    Reduction: 6H++BrO3−→Br−+3H2O6\text{H}^+ + \text{BrO}_3^- \rightarrow \text{Br}^- + 3\text{H}_2\text{O} (6 hydrogen atoms on the right in 3 H2O\text{H}_2\text{O}, so add 6 H+\text{H}^+ on the left)

  5. Balance the charges by adding electrons (e−\text{e}^-).

    Oxidation:
    Left side charge: 0
    Right side charge: +2+2
    To balance, add 2 electrons to the right:

    Zn→Zn2++2e−\text{Zn} \rightarrow \text{Zn}^{2+} + 2\text{e}^-

    Reduction:
    Left side charge: (+6)+(−1)=+5(+6) + (-1) = +5
    Right side charge: (−1)+(0)=−1(-1) + (0) = -1
    To balance, add 6 electrons to the left:

    6e−+6H++BrO3−→Br−+3H2O6\text{e}^- + 6\text{H}^+ + \text{BrO}_3^- \rightarrow \text{Br}^- + 3\text{H}_2\text{O}
  6. Multiply the half-reactions to equalize the number of electrons.

    The oxidation half-reaction has 2 electrons, and the reduction half-reaction has 6 electrons. Multiply the oxidation half-reaction by 3:

    3×(Zn→Zn2++2e−)⇒3Zn→3Zn2++6e−3 \times (\text{Zn} \rightarrow \text{Zn}^{2+} + 2\text{e}^-) \Rightarrow 3\text{Zn} \rightarrow 3\text{Zn}^{2+} + 6\text{e}^-

    The reduction half-reaction remains unchanged:

    6e−+6H++BrO3−→Br−+3H2O6\text{e}^- + 6\text{H}^+ + \text{BrO}_3^- \rightarrow \text{Br}^- + 3\text{H}_2\text{O}
  7. Add the half-reactions and cancel common terms.

    3Zn+(6e−+6H++BrO3−)→(3Zn2++6e−)+(Br−+3H2O)3\text{Zn} + (6\text{e}^- + 6\text{H}^+ + \text{BrO}_3^-) \rightarrow (3\text{Zn}^{2+} + 6\text{e}^-) + (\text{Br}^- + 3\text{H}_2\text{O})

    Cancel the 6 electrons from both sides to get the balanced equation:

    3Zn+6H++BrO3−→3Zn2++Br−+3H2O3\text{Zn} + 6\text{H}^+ + \text{BrO}_3^- \rightarrow 3\text{Zn}^{2+} + \text{Br}^- + 3\text{H}_2\text{O}
  8. Verify the balance of atoms and charges.

    Atoms:
    Zn: 3 on left, 3 on right (balanced)
    Br: 1 on left, 1 on right (balanced)
    O: 3 on left, 3 on right (balanced)
    H: 6 on left, 6 on right (balanced)

    Charges:
    Left side: 0+(+6)+(−1)=+50 + (+6) + (-1) = +5
    Right side: 3×(+2)+(−1)+0=+6−1=+53 \times (+2) + (-1) + 0 = +6 - 1 = +5
    The charges are balanced.

    The balanced redox equation is:

    3Zn+6H++BrO3−→3Zn2++Br−+3H2O\boxed{3\text{Zn} + 6\text{H}^+ + \text{BrO}_3^- \rightarrow 3\text{Zn}^{2+} + \text{Br}^- + 3\text{H}_2\text{O}}
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