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Given an expression relating the Celsius scale and Kelvin scale. Write an expression for the root mean square speed of a gas.

Biology

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1. Given an expression relating the Celsius scale and Kelvin scale. Write an expression for the root mean square speed of a gas.

  • Relationship between Celsius and Kelvin scales: The temperature in Kelvin (TKT_K) is related to the temperature in Celsius (TCT_C) by the following expression:

    TK=TC+273.15T_K = T_C + 273.15
  • Expression for the root mean square (RMS) speed of a gas: The root mean square speed (vrmsv_{rms}) of gas molecules is given by the formula:

    vrms=3RTMv_{rms} = \sqrt{\frac{3RT}{M}}

    where:

    • RR is the ideal gas constant (8.314 J mol−1 K−18.314 \text{ J mol}^{-1} \text{ K}^{-1})
    • TT is the absolute temperature in Kelvin
    • MM is the molar mass of the gas in kg mol−1\text{kg mol}^{-1}

2. Calculate the root mean square speed of hydrogen molecule at 300K (molar mass of hydrogen is 2.016 g/mol, R = 8.314 J mol⁻¹ K⁻¹).

  1. Identify the given values and convert units if necessary.

    • Temperature, T=300 KT = 300 \text{ K}
    • Molar mass of hydrogen (H₂), M=2.016 g/molM = 2.016 \text{ g/mol}
    • Ideal gas constant, R=8.314 J mol−1 K−1R = 8.314 \text{ J mol}^{-1} \text{ K}^{-1}

    Convert the molar mass from g/mol to kg/mol:

    M=2.016 g/mol×1 kg1000 g=0.002016 kg/molM = 2.016 \text{ g/mol} \times \frac{1 \text{ kg}}{1000 \text{ g}} = 0.002016 \text{ kg/mol}
  2. Use the formula for root mean square speed.

    vrms=3RTMv_{rms} = \sqrt{\frac{3RT}{M}}
  3. Substitute the values into the formula and calculate.

    vrms=3×8.314 J mol−1 K−1×300 K0.002016 kg mol−1v_{rms} = \sqrt{\frac{3 \times 8.314 \text{ J mol}^{-1} \text{ K}^{-1} \times 300 \text{ K}}{0.002016 \text{ kg mol}^{-1}}} vrms=7482.6 J mol−10.002016 kg mol−1v_{rms} = \sqrt{\frac{7482.6 \text{ J mol}^{-1}}{0.002016 \text{ kg mol}^{-1}}}

    Since 1 J=1 kg m2 s−21 \text{ J} = 1 \text{ kg m}^2 \text{ s}^{-2}:

    vrms=7482.6 kg m2 s−20.002016 kgv_{rms} = \sqrt{\frac{7482.6 \text{ kg m}^2 \text{ s}^{-2}}{0.002016 \text{ kg}}} vrms=3711607.142857 m2 s−2v_{rms} = \sqrt{3711607.142857 \text{ m}^2 \text{ s}^{-2}} vrms≈1926.558 m/sv_{rms} \approx 1926.558 \text{ m/s}
  4. Round the answer to an appropriate number of significant figures (e.g., 4 significant figures).

    vrms≈1927 m/sv_{rms} \approx 1927 \text{ m/s}

    The root mean square speed of hydrogen molecules at 300 K is:

    1927 m/s\boxed{1927 \text{ m/s}}
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