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1, write the rate law of the reaction 2 derived the rate law 3 derived the order of the reaction
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The general rate law for the reaction is:
where are the orders of reaction with respect to A, B, and C, respectively.
Determine the order with respect to [B] ()
To find , we compare experiments where [A] and [C] are constant, but [B] changes.
Comparing Experiment 1 and Experiment 2:This means . The reaction is zero order with respect to B.
Determine the order with respect to [C] ()
To find , we compare experiments where [A] and [B] are constant, but [C] changes.
Comparing Experiment 1 and Experiment 4:This means . The reaction is first order with respect to C.
Determine the order with respect to [A] ()
To find , we compare experiments where [B] and [C] are constant (or where changes in [B] don't affect the rate since ), but [A] changes.
Comparing Experiment 1 and Experiment 3, using and :This means . The reaction is first order with respect to A.
1. Write the rate law of the reaction
Based on the orders determined ():2. Derived the rate law
This involves finding the orders of reaction for each reactant (as shown in Steps 1-3) and then calculating the rate constant ().
Using the rate law and data from Experiment 1:3. Derived the order of the reaction
The overall order of the reaction is the sum of the individual orders ():The overall order of the reaction is:
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