This chemistry question involves key chemical concepts and calculations. The detailed solution below walks through each step, from identifying the reaction type to computing the final answer.

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33.33 years
Welcome back ADAM — missed you this week.
1a) The term half-life refers to the time required for half of the radioactive nuclei in a sample to undergo radioactive decay.
1b) Step 1: Determine the number of half-lives (). The formula for radioactive decay is , where is the final mass, is the initial mass, and is the number of half-lives. To find , we recognize that .
Step 2: Calculate the half-life (). The total time () is related to the number of half-lives () and the half-life () by the formula .
2i) The balanced chemical equation is: According to Gay-Lussac's Law of Combining Volumes, the ratio of the volumes of reacting gases and gaseous products is given by their stoichiometric coefficients, assuming constant temperature and pressure.
Step 1: Determine the volume of Nitrogen used. From the equation, 3 volumes of H react with 1 volume of N. \text{Volume of N}_2 = 266.67 \text{ cm^3}
Step 2: Determine the volume of Ammonia produced. From the equation, 3 volumes of H produce 2 volumes of NH. \text{Volume of NH}_3 = 533.33 \text{ cm^3}
2ii) The reaction is exothermic (). If the temperature is lowered from to : • According to Le Chatelier's principle, lowering the temperature for an exothermic reaction will shift the equilibrium position to the right, favoring the formation of more ammonia (products). • However, lowering the temperature also decreases the kinetic energy of the reactant molecules, which leads to fewer effective collisions and thus a slower reaction rate.
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Welcome back ADAM — missed you this week. 1a) The term half-life refers to the time required for half of the radioactive nuclei in a sample to undergo radioactive decay.
This chemistry question involves key chemical concepts and calculations. The detailed solution below walks through each step, from identifying the reaction type to computing the final answer.