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When 56.6 g of calcium and 30.5 g of nitrogen gas undergo a reaction that has a 93.0% yield, what mass (g) of calcium nitride is formed?

Chemistry

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Answer

64.9 g\text{64.9 g}

Step-by-step solution

6 steps
  1. Write the balanced chemical equation for the reaction.

    Calcium (Ca) reacts with Nitrogen gas (N₂) to form Calcium nitride (Ca₃N₂).

    3Ca(s)+N2(g)→Ca3N2(s)3\text{Ca(s)} + \text{N}_2\text{(g)} \rightarrow \text{Ca}_3\text{N}_2\text{(s)}
  2. Calculate the molar masses of the reactants and the product.

    • Molar mass of Ca = 40.08 g/mol40.08 \text{ g/mol}
    • Molar mass of N₂ = 2×14.01 g/mol=28.02 g/mol2 \times 14.01 \text{ g/mol} = 28.02 \text{ g/mol}
    • Molar mass of Ca₃N₂ = (3×40.08 g/mol)+(2×14.01 g/mol)=120.24 g/mol+28.02 g/mol=148.26 g/mol(3 \times 40.08 \text{ g/mol}) + (2 \times 14.01 \text{ g/mol}) = 120.24 \text{ g/mol} + 28.02 \text{ g/mol} = 148.26 \text{ g/mol}
  3. Convert the given masses of reactants to moles.

    • Moles of Ca = 56.6 g40.08 g/mol=1.4122 mol Ca\frac{56.6 \text{ g}}{40.08 \text{ g/mol}} = 1.4122 \text{ mol Ca}
    • Moles of N₂ = 30.5 g28.02 g/mol=1.0885 mol N2\frac{30.5 \text{ g}}{28.02 \text{ g/mol}} = 1.0885 \text{ mol N}_2
  4. Determine the limiting reactant.

    Using the stoichiometric ratio from the balanced equation (3 mol Ca:1 mol N23 \text{ mol Ca} : 1 \text{ mol N}_2):

    • To react all 1.4122 mol Ca1.4122 \text{ mol Ca}, we need:
    1.4122 mol Ca×1 mol N23 mol Ca=0.4707 mol N21.4122 \text{ mol Ca} \times \frac{1 \text{ mol N}_2}{3 \text{ mol Ca}} = 0.4707 \text{ mol N}_2

    Since we have 1.0885 mol N21.0885 \text{ mol N}_2, which is more than 0.4707 mol N20.4707 \text{ mol N}_2, nitrogen is in excess. Therefore, Calcium (Ca) is the limiting reactant.

  5. Calculate the theoretical yield of Calcium nitride (Ca₃N₂).

    The theoretical yield is based on the limiting reactant, Ca. From the balanced equation, 3 mol Ca3 \text{ mol Ca} produces 1 mol Ca3N21 \text{ mol Ca}_3\text{N}_2.

    • Moles of Ca₃N₂ produced = 1.4122 mol Ca×1 mol Ca3N23 mol Ca=0.4707 mol Ca3N21.4122 \text{ mol Ca} \times \frac{1 \text{ mol Ca}_3\text{N}_2}{3 \text{ mol Ca}} = 0.4707 \text{ mol Ca}_3\text{N}_2
    • Mass of Ca₃N₂ (theoretical) = 0.4707 mol×148.26 g/mol=69.79 g Ca3N20.4707 \text{ mol} \times 148.26 \text{ g/mol} = 69.79 \text{ g Ca}_3\text{N}_2
  6. Calculate the actual mass of Calcium nitride formed using the given percent yield.

    The percent yield is 93.0%93.0\%.

    Actual yield=Theoretical yield×Percent yield100%\text{Actual yield} = \text{Theoretical yield} \times \frac{\text{Percent yield}}{100\%} Actual yield=69.79 g×93.0100=69.79 g×0.930=64.9047 g\text{Actual yield} = 69.79 \text{ g} \times \frac{93.0}{100} = 69.79 \text{ g} \times 0.930 = 64.9047 \text{ g}

    Rounding to three significant figures, the actual mass of calcium nitride formed is 64.9 g64.9 \text{ g}.

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