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A student performs a titration. They use solution K to neutralise solution L. Use the data to determine the concentration of solution L in moles per litre.

Chemistry

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Step 1: Calculate the volume of solution K used for each trial.

  • Trial I: Volume used = Final reading - Initial reading = 5.0 cm3−0.0 cm3=5.0 cm35.0 \, \text{cm}^3 - 0.0 \, \text{cm}^3 = 5.0 \, \text{cm}^3
  • Trial II: Volume used = Final reading - Initial reading = 10.1 cm3−5.0 cm3=5.1 cm310.1 \, \text{cm}^3 - 5.0 \, \text{cm}^3 = 5.1 \, \text{cm}^3
  • Trial III: Volume used = Final reading - Initial reading = 15.3 cm3−10.1 cm3=5.2 cm315.3 \, \text{cm}^3 - 10.1 \, \text{cm}^3 = 5.2 \, \text{cm}^3

Step 2: Calculate the average volume of solution K used.
The concordant titres are 5.1 cm35.1 \, \text{cm}^3 and 5.2 cm35.2 \, \text{cm}^3. We average these values.

Average volume of K=5.1 cm3+5.2 cm32\text{Average volume of K} = \frac{5.1 \, \text{cm}^3 + 5.2 \, \text{cm}^3}{2} Average volume of K=10.3 cm32\text{Average volume of K} = \frac{10.3 \, \text{cm}^3}{2} Average volume of K=5.15 cm3\text{Average volume of K} = 5.15 \, \text{cm}^3

The average volume of solution K used is 5.15 cm3\boxed{\text{5.15 cm}^3}.

b) Determine the concentration of solution L in moles per litre.

Step 1: Calculate the molar mass of sodium hydroxide (NaOH).
Given atomic masses: Na=23Na = 23, O=16O = 16, H=1H = 1.

Mr(NaOH)=23+16+1=40 g/molM_r(NaOH) = 23 + 16 + 1 = 40 \, \text{g/mol}

Step 2: Calculate the concentration of solution L (NaOH) in moles per litre.
Solution L contains 2 g2 \, \text{g} of NaOH per litre.

Concentration of L=Mass concentrationMolar mass\text{Concentration of L} = \frac{\text{Mass concentration}}{\text{Molar mass}} Concentration of L=2 g/L40 g/mol\text{Concentration of L} = \frac{2 \, \text{g/L}}{40 \, \text{g/mol}} Concentration of L=0.05 mol/L\text{Concentration of L} = 0.05 \, \text{mol/L}

The concentration of solution L is 0.05 mol/L\boxed{\text{0.05 mol/L}}.

c) Determine the number of moles of solution L that reacted with solution K.

Step 1: Convert the volume of solution L from cm3\text{cm}^3 to litres.
The volume of solution L pipetted was 25 cm325 \, \text{cm}^3.

Volume of L=25 cm3=251000 L=0.025 L\text{Volume of L} = 25 \, \text{cm}^3 = \frac{25}{1000} \, \text{L} = 0.025 \, \text{L}

Step 2: Calculate the number of moles of solution L.

Moles of L=Concentration of L×Volume of L\text{Moles of L} = \text{Concentration of L} \times \text{Volume of L}
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