c) To identify the two solutions:
Step 1: Add dilute hydrochloric acid to a small portion of each unknown solution.
• The solution containing sulphite ions will produce a colorless gas with a pungent smell (SO2), which turns acidified potassium dichromate(VI) solution from orange to green.
SO32−(aq)+2H+(aq)→SO2(g)+H2O(l)
• The solution containing sulphate ions will show no visible reaction.
Step 2: To the solution that showed no reaction with dilute hydrochloric acid (from Step 1), add a few drops of barium chloride solution.
• A white precipitate will form, which is insoluble in dilute hydrochloric acid. This confirms the presence of sulphate ions.
Ba2+(aq)+SO42−(aq)→BaSO4(s)
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a) Isomers are compounds that have the same molecular formula but different structural formulas or different arrangements of atoms in space.
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b) The molecular formula C4H10 has two isomers:
• Butane
CH3CH2CH2CH3
• 2-Methylpropane
CH3CH(CH3)CH3
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c)
i) • Chlorination of ethane: Free radical substitution
• Chlorination of ethene: Electrophilic addition
ii) A condition necessary for chlorination of ethane is ultraviolet (UV) light or high temperature.
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d) Two uses of ethene gas are:
• For the ripening of fruits.
• In the manufacture of polyethene (a plastic).
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e) Heat of combustion of a substance is the heat energy released when one mole of a substance undergoes complete combustion in excess oxygen under standard conditions.
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