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Assumption: We will assume the average volume of solution A (H2SO4) used in the titration (V_A) is 20.00 cm3.
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To solve this problem, we first need to address the missing titration data. Since no experimental readings are provided for the titration, we will assume a typical average volume of solution A used.
Assumption: We will assume the average volume of solution A (HSO) used in the titration () is \textbf{20.00 cm^3}.
i) Concentration of B in mol/dm
Step 1: Calculate the molar mass of Sodium hydroxide (NaOH).
The relative atomic masses are H=1.00, O=16.0, Na=23.0.
Step 2: Calculate the number of moles of NaOH in 1 g.
Step 3: Calculate the concentration of solution B (NaOH) in mol/dm.
The volume of solution B is 250 cm, which is 0.250 dm.
ii) Concentration of A in mol/dm
Step 4: Write the balanced chemical equation and determine the mole ratio.
The balanced equation is:
From the equation, 1 mole of HSO reacts with 2 moles of NaOH. So, and .
Step 5: Use the titration formula to calculate the concentration of A (HSO).
Given:
(from part i)
(assumed average volume)
The titration formula is:
Rearranging to solve for :
iii) Number of hydrogen ions in 1.0 dm of A
Step 6: Calculate the moles of HSO in 1.0 dm of solution A.
The concentration of A () is 0.0625 mol/dm.
Step 7: Determine the moles of hydrogen ions (H) produced.
Sulfuric acid (HSO) is a strong acid and dissociates completely in water:
Each mole of HSO produces 2 moles of H ions.
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