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Calculate the average accurate titre volume of aqueous silver nitrate (AgNO₃).

Chemistry

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Answer

29.9

0.1196 M\text{0.1196 M}

Step-by-step solution

6 steps
  1. Calculate the average accurate titre volume of aqueous silver nitrate (AgNO3\text{AgNO}_3).

    The accurate titre readings are 30.0 cm330.0 \text{ cm}^3 and 29.8 cm329.8 \text{ cm}^3.

    Average titre=30.0 cm3+29.8 cm32=59.8 cm32=29.9 cm3\text{Average titre} = \frac{30.0 \text{ cm}^3 + 29.8 \text{ cm}^3}{2} = \frac{59.8 \text{ cm}^3}{2} = 29.9 \text{ cm}^3
  2. Fill in the blank statement.

    The average titre is 29.9 cm329.9 \text{ cm}^3.

    Therefore, 29.9\boxed{29.9} cm3\text{cm}^3 titre (t) of aqueous silver nitrate reacts with 25.0 cm325.0 \text{ cm}^3 of aqueous hydrochloric acid.

  3. Write the balanced chemical equation for the reaction between hydrochloric acid (HCl) and silver nitrate (AgNO3\text{AgNO}_3).

    The reaction is a precipitation reaction where silver ions react with chloride ions.

    AgNO3(aq)+HCl(aq)⟶AgCl(s)+HNO3(aq)\text{AgNO}_3(\text{aq}) + \text{HCl}(\text{aq}) \longrightarrow \text{AgCl}(\text{s}) + \text{HNO}_3(\text{aq})

    From the equation, the mole ratio of AgNO3\text{AgNO}_3 to HCl is 1:11:1.

  4. Calculate the moles of AgNO3\text{AgNO}_3 used.

    Given concentration of AgNO3=0.1 M\text{AgNO}_3 = 0.1 \text{ M}.
    Volume of AgNO3\text{AgNO}_3 used (average titre) =29.9 cm3=29.9×10−3 dm3= 29.9 \text{ cm}^3 = 29.9 \times 10^{-3} \text{ dm}^3.

    Moles of AgNO3=Concentration×Volume\text{Moles of AgNO}_3 = \text{Concentration} \times \text{Volume} Moles of AgNO3=0.1 mol/dm3×29.9×10−3 dm3\text{Moles of AgNO}_3 = 0.1 \text{ mol/dm}^3 \times 29.9 \times 10^{-3} \text{ dm}^3 Moles of AgNO3=2.99×10−3 mol\text{Moles of AgNO}_3 = 2.99 \times 10^{-3} \text{ mol}
  5. Calculate the moles of HCl reacted.

    Since the mole ratio of AgNO3:HCl\text{AgNO}_3 : \text{HCl} is 1:11:1:

    Moles of HCl=Moles of AgNO3=2.99×10−3 mol\text{Moles of HCl} = \text{Moles of AgNO}_3 = 2.99 \times 10^{-3} \text{ mol}
  6. Calculate the concentration of HCl.

    Volume of HCl used =25.0 cm3=25.0×10−3 dm3= 25.0 \text{ cm}^3 = 25.0 \times 10^{-3} \text{ dm}^3.

    Concentration of HCl=Moles of HClVolume of HCl\text{Concentration of HCl} = \frac{\text{Moles of HCl}}{\text{Volume of HCl}} Concentration of HCl=2.99×10−3 mol25.0×10−3 dm3\text{Concentration of HCl} = \frac{2.99 \times 10^{-3} \text{ mol}}{25.0 \times 10^{-3} \text{ dm}^3} Concentration of HCl=2.9925.0 mol/dm3\text{Concentration of HCl} = \frac{2.99}{25.0} \text{ mol/dm}^3 Concentration of HCl=0.1196 mol/dm3\text{Concentration of HCl} = 0.1196 \text{ mol/dm}^3

    The concentration of hydrochloric acid is 0.1196 M\boxed{\text{0.1196 M}}.

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