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Step 1: Calculate the average accurate titre volume of aqueous silver nitrate (AgNO3β).
The accurate titre readings are 30.0cm3 and 29.8cm3.
Averagetitre=230.0cm3+29.8cm3β=259.8cm3β=29.9cm3
Step 2: Fill in the blank statement.
The average titre is 29.9cm3.
Therefore, 29.9β cm3 titre (t) of aqueous silver nitrate reacts with 25.0cm3 of aqueous hydrochloric acid.
Step 3: Write the balanced chemical equation for the reaction between hydrochloric acid (HCl) and silver nitrate (AgNO3β).
The reaction is a precipitation reaction where silver ions react with chloride ions.
AgNO3β(aq)+HCl(aq)βΆAgCl(s)+HNO3β(aq)
From the equation, the mole ratio of AgNO3β to HCl is 1:1.
Step 4: Calculate the moles of AgNO3β used.
Given concentration of AgNO3β=0.1Β M.
Volume of AgNO3β used (average titre) =29.9cm3=29.9Γ10β3dm3.
MolesofAgNO3β=ConcentrationΓVolume
MolesofAgNO3β=0.1mol/dm3Γ29.9Γ10β3dm3
MolesofAgNO3β=2.99Γ10β3mol
Step 5: Calculate the moles of HCl reacted.
Since the mole ratio of AgNO3β:HCl is 1:1:
MolesofHCl=MolesofAgNO3β=2.99Γ10β3mol
Step 6: Calculate the concentration of HCl.
Volume of HCl used =25.0cm3=25.0Γ10β3dm3.
ConcentrationofHCl=VolumeofHClMolesofHClβ
ConcentrationofHCl=25.0Γ10β3dm32.99Γ10β3molβ
ConcentrationofHCl=25.02.99βmol/dm3
ConcentrationofHCl=0.1196mol/dm3
The concentration of hydrochloric acid is 0.1196Mβ.
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