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Balance each of the equations below, and identify the type of reaction in each case:

Chemistry

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here are the balanced equations and their reaction types:

Part a(i)· 3 steps

Al4(CO3)3→Al2O3+CO\text{Al}_4(\text{CO}_3)_3 \rightarrow \text{Al}_2\text{O}_3 + \text{CO}

Balance each of the equations below, and identify the type of reaction in each case

  1. Balance Al atoms.

    There are 4 Al on the left, so place a coefficient of 2 in front of Al2O3\text{Al}_2\text{O}_3.

    Al4(CO3)3→2Al2O3+CO\text{Al}_4(\text{CO}_3)_3 \rightarrow 2\text{Al}_2\text{O}_3 + \text{CO}
  2. Balance C atoms.

    There are 3 C on the left, so place a coefficient of 3 in front of CO\text{CO}.

    Al4(CO3)3→2Al2O3+3CO\text{Al}_4(\text{CO}_3)_3 \rightarrow 2\text{Al}_2\text{O}_3 + 3\text{CO}
  3. Check O atoms.

    Left: 3×3=93 \times 3 = 9. Right: (2×3)+(3×1)=6+3=9(2 \times 3) + (3 \times 1) = 6 + 3 = 9. All atoms are balanced.
    Balanced Equation: Al4(CO3)3→2Al2O3+3CO\boxed{\text{Al}_4(\text{CO}_3)_3 \rightarrow 2\text{Al}_2\text{O}_3 + 3\text{CO}}
    Type of Reaction: Decomposition reaction (one compound breaks down into simpler substances).

Part a(ii)· 1 step

BaO2+H2SO4→BaSO4+H2O\text{BaO}_2 + \text{H}_2\text{SO}_4 \rightarrow \text{BaSO}_4 + \text{H}_2\text{O}

Assumption: Based on common chemical reactions, the product H2O\text{H}_2\text{O} is likely a typo and should be H2O2\text{H}_2\text{O}_2 (hydrogen peroxide), as barium peroxide reacts with sulfuric acid to produce barium sulfate and hydrogen peroxide. The equation does not balance with H2O\text{H}_2\text{O} as a product.

  1. Assuming the product is H2O2\text{H}_2\text{O}_2, let's check the atoms.

    Reactants: Ba: 1, O: 2+4=62+4=6, H: 2, S: 1
    Products: Ba: 1, O: 4+2=64+2=6, H: 2, S: 1
    All atoms are already balanced.
    Balanced Equation: BaO2+H2SO4→BaSO4+H2O2\boxed{\text{BaO}_2 + \text{H}_2\text{SO}_4 \rightarrow \text{BaSO}_4 + \text{H}_2\text{O}_2}
    Type of Reaction: Double displacement reaction (ions are exchanged between two compounds).

Part a(iii)· 2 steps

Ba(ClO3)2→BaCl2+O2\text{Ba}(\text{ClO}_3)_2 \rightarrow \text{BaCl}_2 + \text{O}_2

  1. Balance O atoms.

    There are 6 O on the left, so place a coefficient of 3 in front of O2\text{O}_2.

    Ba(ClO3)2→BaCl2+3O2\text{Ba}(\text{ClO}_3)_2 \rightarrow \text{BaCl}_2 + 3\text{O}_2
  2. Check Ba and Cl atoms.

    Ba: 1 on both sides. Cl: 2 on both sides. All atoms are balanced.
    Balanced Equation: Ba(ClO3)2→BaCl2+3O2\boxed{\text{Ba}(\text{ClO}_3)_2 \rightarrow \text{BaCl}_2 + 3\text{O}_2}
    Type of Reaction: Decomposition reaction (one compound breaks down into simpler substances).

Part a(iv)· 5 steps

Cu+HNO3→Cu(NO3)2+NO+H2O\text{Cu} + \text{HNO}_3 \rightarrow \text{Cu}(\text{NO}_3)_2 + \text{NO} + \text{H}_2\text{O}

  1. This is a redox reaction.

    Balance the oxidation and reduction changes. Cu goes from 0 to +2 (oxidized, change of +2). N goes from +5 in HNO3\text{HNO}_3 to +2 in NO\text{NO} (reduced, change of -3). To balance electrons, we need 3 Cu and 2 NO.

  2. Start by placing coefficients for Cu and NO

    3Cu+HNO3→3Cu(NO3)2+2NO+H2O3\text{Cu} + \text{HNO}_3 \rightarrow 3\text{Cu}(\text{NO}_3)_2 + 2\text{NO} + \text{H}_2\text{O}
  3. Balance N atoms.

    On the right, there are 3×2=63 \times 2 = 6 N in Cu(NO3)2\text{Cu}(\text{NO}_3)_2 and 2 N in NO\text{NO}, totaling 8 N. So, place a coefficient of 8 in front of HNO3\text{HNO}_3.

    3Cu+8HNO3→3Cu(NO3)2+2NO+H2O3\text{Cu} + 8\text{HNO}_3 \rightarrow 3\text{Cu}(\text{NO}_3)_2 + 2\text{NO} + \text{H}_2\text{O}
  4. Balance H atoms.

    There are 8 H on the left. On the right, we need 8 H, so place a coefficient of 4 in front of H2O\text{H}_2\text{O}.

    3Cu+8HNO3→3Cu(NO3)2+2NO+4H2O3\text{Cu} + 8\text{HNO}_3 \rightarrow 3\text{Cu}(\text{NO}_3)_2 + 2\text{NO} + 4\text{H}_2\text{O}
  5. Check O atoms.

    Left: 8×3=248 \times 3 = 24. Right: (3×2×3)+(2×1)+(4×1)=18+2+4=24(3 \times 2 \times 3) + (2 \times 1) + (4 \times 1) = 18 + 2 + 4 = 24. All atoms are balanced.
    Balanced Equation: 3Cu+8HNO3→3Cu(NO3)2+2NO+4H2O\boxed{3\text{Cu} + 8\text{HNO}_3 \rightarrow 3\text{Cu}(\text{NO}_3)_2 + 2\text{NO} + 4\text{H}_2\text{O}}
    Type of Reaction: Redox reaction (oxidation states of elements change).

Part a(v)· 3 steps

H3BO3→H3B3O6+H2O\text{H}_3\text{BO}_3 \rightarrow \text{H}_3\text{B}_3\text{O}_6 + \text{H}_2\text{O}

  1. Balance B atoms.

    There is 1 B on the left and 3 B on the right, so place a coefficient of 3 in front of H3BO3\text{H}_3\text{BO}_3.

    3H3BO3→H3B3O6+H2O3\text{H}_3\text{BO}_3 \rightarrow \text{H}_3\text{B}_3\text{O}_6 + \text{H}_2\text{O}
  2. Balance H and O atoms.

    Reactants: H: 3×3=93 \times 3 = 9, O: 3×3=93 \times 3 = 9.
    Products: H: 3 (from H3B3O6\text{H}_3\text{B}_3\text{O}_6) + 2 (from H2O\text{H}_2\text{O}) = 5. O: 6 (from H3B3O6\text{H}_3\text{B}_3\text{O}_6) + 1 (from H2O\text{H}_2\text{O}) = 7.
    We need 9−3=69-3=6 more H and 9−6=39-6=3 more O on the product side. This corresponds to 3 molecules of H2O\text{H}_2\text{O}. So, change the coefficient of H2O\text{H}_2\text{O} to 3.

    3H3BO3→H3B3O6+3H2O3\text{H}_3\text{BO}_3 \rightarrow \text{H}_3\text{B}_3\text{O}_6 + 3\text{H}_2\text{O}
  3. Check all atoms.

    Reactants: H: 9, B: 3, O: 9.
    Products: H: 3+(3×2)=93 + (3 \times 2) = 9, B: 3, O: 6+(3×1)=96 + (3 \times 1) = 9. All atoms are balanced.
    Balanced Equation: 3H3BO3→H3B3O6+3H2O\boxed{3\text{H}_3\text{BO}_3 \rightarrow \text{H}_3\text{B}_3\text{O}_6 + 3\text{H}_2\text{O}}
    Type of Reaction: Decomposition reaction (specifically, a dehydration reaction where water is removed).

Part a(vi)· 6 steps

P4+P2+H2O→PH4I+H3PO4\text{P}_4 + \text{P}_2 + \text{H}_2\text{O} \rightarrow \text{PH}_4\text{I} + \text{H}_3\text{PO}_4

Assumption: The reactant P2\text{P}_2 is likely a typo for I2\text{I}_2 (iodine), as P2\text{P}_2 is not a common stable reactant and the product PH4I\text{PH}_4\text{I} contains iodine. We will balance the reaction: P4+I2+H2O→PH4I+H3PO4\text{P}_4 + \text{I}_2 + \text{H}_2\text{O} \rightarrow \text{PH}_4\text{I} + \text{H}_3\text{PO}_4. This is a disproportionation reaction of phosphorus.

  1. Balance P, I, H, and O atoms using a system of equations or by inspection.

    Let the coefficients be aP4+bI2+cH2O→dPH4I+eH3PO4a\text{P}_4 + b\text{I}_2 + c\text{H}_2\text{O} \rightarrow d\text{PH}_4\text{I} + e\text{H}_3\text{PO}_4.
    P: 4a=d+e4a = d+e
    I: 2b=d2b = d
    H: 2c=4d+3e2c = 4d+3e
    O: c=4ec = 4e

  2. From c=4ec=4e, substitute into the H equation

    2(4e)=4d+3e  ⟹  8e=4d+3e  ⟹  5e=4d2(4e) = 4d+3e \implies 8e = 4d+3e \implies 5e = 4d.

  3. To find integer coefficients, let d=5kd=5k and e=4ke=4k.

    The smallest integers for dd and ee that satisfy 5e=4d5e=4d are d=5d=5 and e=4e=4.

  4. Substitute d=5d=5 and e=4e=4 into the other equations.

    From I: 2b=5  ⟹  b=2.52b = 5 \implies b = 2.5.
    From P: 4a=5+4  ⟹  4a=9  ⟹  a=2.254a = 5+4 \implies 4a = 9 \implies a = 2.25.

  5. To get whole numbers, multiply all coefficients by 4 (the least common multiple of the denominators for aa and bb).

    a=2.25×4=9a = 2.25 \times 4 = 9
    b=2.5×4=10b = 2.5 \times 4 = 10
    d=5×4=20d = 5 \times 4 = 20
    e=4×4=16e = 4 \times 4 = 16

  6. Calculate cc using c=4ec=4e

    c=4×16=64c = 4 \times 16 = 64.
    Balanced Equation: 9P4+10I2+64H2O→20PH4I+16H3PO4\boxed{9\text{P}_4 + 10\text{I}_2 + 64\text{H}_2\text{O} \rightarrow 20\text{PH}_4\text{I} + 16\text{H}_3\text{PO}_4}
    Type of Reaction: Redox reaction (specifically, a disproportionation reaction where phosphorus is both oxidized and reduced).

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